A series of transition metal complexes of Cu(II), Ru(II), Fe(II), Mo(II) with a tetradentate ligand, bis (2-hydroxy benzylidene) benzidine prepared by the condensation of 2-hydroxy benzaldehyde and benzidine. Metal complexes are reported and characterized based on elemental analysis IR, HNMR, Magnetic moment, molar conductance and thermal analysis. The synthesized ligands in comparison to their...

A mixed ligand Cd(II) complex [Cd(IsoPht)(TEA)H2O]·3H2O was synthesized for the first time by using isophthalic acid (H2IsoPht) and tetradentate triethanolamine (TEA) characterized X-ray single-crystal diffraction, FT-IR, thermogravimetric analysis (TGA). This novel crystallizes in triclinic system with P-1 space group distorted monocapped trigonal prismatic geometry. The has seven coordinates ...

Tetradentate complexes of Zn (II) Schiff bases derived from DHA, o-phenylenediamine, 4- N, Diethyl amino Salicylaldehyde (L1) and Dehydroacetic Acid (DHA), 4-methyl-o-phenylenediamine, 5-bromo (L2) have been synthesized characterized by elemental analysis, magnetic susceptibility, thermal X-ray diffraction, 1HNMR, Mass, IR,UV visible spectra conductometry. The ligand field parameters found to o...

The pendent-arm macrocyclic hexaamine trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine (L) may coordinate in tetra-, penta- or hexadentate modes, depending on the metal ion and the synthetic procedure. We report here the crystal structures of two pseudo-octahedral cobalt(III) complexes of L, namely sodium trans-cyano(trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-d...

In the title compound, [Ni(C8H14N6S2)], the Ni(II) ion is coordinated by N2S2 donor atoms of the tetradentate thio-semicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related mol-ecules are linked via pairs of N-H⋯N and N-H⋯S hydrogen bonds, forming R 2 (2)(8) ring motifs. Mol-ecules are further linked by slightly weaker N-H⋯N, N-H⋯S and C-H⋯S hy...

Organometallic Ni(III) intermediates have been proposed in several Nickel-catalyzed cross-coupling reactions, yet no isolated bis(hydrocarbyl)Ni(III) complexes have been reported to date. Herein we report the synthesis and detailed characterization of stable organometallic Ni(III) complexes that contain two trifluoromethyl ligands and are supported by tetradentate N-donor ligands (R)N4 (R = Me ...

90 A practical method of olefin epoxidation was developed by combining FeCl3·6H2O and 1methylimidazole in acetone using H2O2 as the terminal oxidant. This system showed very good reactivity toward epoxidation of both terminal and substituted alkenes. The use of tridentate and tetradentate amine-bis(phenolate) ligands as additives was also examined. Modest improvement in selectivity was achieved...

Technetium-99m labeling of antibodies has been suboptimal because of low affinity adventitious binding, nonspecific labeling, and loss of immunoreactivity. The diamide dithiolate ligand system (N2S2) forms highly stable, well-defined tetradentate complexes with Tc(V). Antibodies and their fragments have been labeled by conjugation of preformed 99mTc-4,5-bis(thioacetamido)pentanoate active ester...