We investigated hellandite-group mineral phases from the Roman Region, alkali syenite ejecta, by multimethod analyses. They show a complex crystallisation history including co-precipitation of hellandite-(Ce) with brockite, resorption, sub-solidus substitution mottanaite-(Ce), exsolution perthite-like ferri-mottanaite-(Ce), overgrowth an oscillatory-zoned euhedral shell ferri-mottanaite-(Ce) an...