A phosphine-free palladium catalyst for aqueous Suzuki-Miyaura cross-coupling is presented. The catalyst is active enough to mediate hindered, ortho-substituted biaryl couplings but mild enough for use on peptides and proteins. The Suzuki-Miyaura couplings on protein substrates are the first to proceed in useful conversions. Notably, hydrophobic aryl and vinyl groups can be transferred to the p...

3. Xu Y, Carr LG, Bosron WF, Li T-K, Edenberg HJ. Genotyping of human alcohol dehydrogenases at the ADH2 and ADH3 loci following DNA sequence amplification. Genomics. 1988;2:209-214. 4. Aoshima T, Umetsu K, Yuasa I, Watanabe G, Suzuki T. Simultaneous genotyping of alcohol dehydrogenase 2 (ADH2) and aldehyde dehydrogenase 2 (ALDH2) loci by amplified product length polymorphism (APLP) analysis. E...

Abstract Chemoselective cross-coupling of phenol derivatives is valuable for generating products that retain halides. Here we discuss recent developments in selective cross-couplings chloroaryl derivatives, with a particular focus on reactions tosylates. The first example C–O-selective Ni-catalyzed Suzuki–Miyaura coupling tosylates discussed detail. 1 Introduction 2 Density Functional Theory St...

We investigate a noncompact Gepner model, which is composed of a number of SL(2,R)/U(1) Kazama-Suzuki models and N = 2 minimal models. The SL(2,R)/U(1) Kazama-Suzuki model contains the discrete series among the SL(2,R) unitary representations as well as the continuous series. We claim that the discrete series contain the vanishing cohomology and the vanishing cycles of the associated noncompact...

Palladacycles are highly efficient precatalysts in cross-coupling reactions whose immobilization on carbonaceous materials has been hardly studied. Herein, we report a detailed study on the synthesis and characterization of new oxime palladacycle-graphene oxide non-covalent materials along with their catalytic activity in the Suzuki–Miyaura reaction. Catalyst 1-GO, which has been fully characte...

In this paper, we study the recently proposed encryption scheme MST3, focusing on a concrete instantiation using Suzuki-2-groups. In a passive scenario, we argue that the one wayness of this scheme may not, as claimed, be proven without the assumption that factoring group elements with respect to random covers for a subset of the group is hard. As a result, we conclude that for the proposed Suz...

Tadashi Suzuki Tojiro Noda Hisae Shibuya, Dr. Info. Hideaki Suzuki OVERVIEW: Combining maintenance service expertise with data mining technology, Hitachi has developed an anomaly detection system to make appropriate diagnoses in accordance with equipment status changes. The system enables automation of equipment status diagnoses that previously required engineers with specialist knowledge. The ...

The direct formation of (hetero)biaryls from readily available (hetero)aryl halides under mild reaction conditions can be efficiently achieved through the Masuda borylation–Suzuki coupling (MBSC) sequence. MBSC sequence catenates Pd-catalyzed borylation and Suzuki into a one-pot process, giving access to diverse symmetrically unsymmetrically substituted scaffolds. (Hetero)biaryls are ubiquitous...

Learning prosodic control for speaking Japanese is effective to reduce syntactic and lexical ambiguity and to improve the comprehensibility of learners’ spoken Japanese. Good prosody can also improve its naturalness. In the conventional curriculum however, prosody training has not been provided satisfactorily for learners partly because of scarcity of teaching materials. To facilitate prosody t...

We construct and study a new near octagon of order (2, 10) which has its full automorphism group isomorphic to the group G2(4) : 2 and which contains 416 copies of the Hall-Janko near octagon as full subgeometries. Using this near octagon and its substructures we give geometric constructions of the G2(4)-graph and the Suzuki graph, both of which are strongly regular graphs contained in the Suzu...