While the importance of sulfur transfer reactions is well established for a number of biosynthetic pathways, evidence has only started to emerge that sulfurtransferases may also be major players in sulfur-based microbial energy metabolism. Among the first organisms studied in this regard is the phototrophic purple sulfur bacterium Allochromatium vinosum. During the oxidation of reduced sulfur s...

Gold nanoparticles (GNPs) are often used as colloidal carriers in numerous applications owing to their low-cost and size-controlled preparation as well as their straightforward surface functionalization with thiol containing molecules forming self-assembling monolayers (SAM). The quantification of the ligand density of such modified GNPs is technically challenging, yet of utmost importance for ...

Sulfur dioxide has two important sources in the atmosphere and this is why most of scientists believe in a geographic split in the globe. Power plants, major emitter of SO2, are located in north hemisphere such as in Russia, China, Canada and the USA. In south hemisphere, phytoplankton produces a massive amount of dimethyl sulfide (DMS) and dimethyl disulfide (DMDS). Then these types of reduced...

Nanoparticles are generally considered excellent candidates for targeted drug delivery. However, ion leakage and cytotoxicity induced by nanoparticle permeation is a potential problem in such drug delivery schemes because of the toxic effect of many ions. In this study, we have carried out a series of coarse-grained molecular dynamics simulations to investigate the water penetration, ion transp...

effect of different amounts of sulfur fertilizer (0, 50, 100, 150, 200, 250 kg/ha) and 200 kg/ha of thiobacillus inoculant on yield, quality and storability of two edible onion cultivars red rey and white qom were investigated. the experiments were conducted at experimental field and laboratories of the department of horticulture, seed and plant improvement institute, karaj, iran in 2007-08 cro...

The commercialization of lithium-sulfur batteries is hindered by low cycle stability and low efficiency, which are induced by sulfur active material loss and polysulfide shuttle reaction through dissolution into electrolyte. In this study, sulfur-impregnated disordered carbon nanotubes are synthesized as cathode material for the lithium-sulfur battery. The obtained sulfur-carbon tube cathodes d...

Sulfur compounds in intermediate valence states, for example elemental sulfur, thiosulfate, and tetrathionate, are important players in the biogeochemical sulfur cycle. However, key understanding about the pathways of oxidation involving mixed-valance state sulfur species is still missing. Here we report the sulfur and oxygen isotope fractionation effects during the oxidation of tetrathionate (...

It is currently assumed that the assimilation of sulfur into reduced forms occurs predominantly in the leaves of plants. However, developing seeds have a strong requirement for sulfur amino acids for storage protein synthesis. We have assessed the capacity of developing seeds of narrow-leaf lupin (Lupinus angustifolius) for sulfur assimilation. Cotyledons of developing lupin seeds were able to ...

Rhodococcus sp. strain ECRD-1 was evaluated for its ability to desulfurize a 232 to 343 degrees C middle-distillate (diesel range) fraction of Oregon basin (OB) crude oil. OB oil was provided as the sole source of sulfur in batch cultures, and the extent of desulfurization and the chemical fate of the residual sulfur in the oil after treatment were determined. Gas chromatography (GC), flame ion...

Traditionally, sulfur responses have been limited to coarse textured or other soils low in organic matter that have little potential for sulfur mineralization. In the past, the burning of fossil fuels has contributed a significant amount of sulfur through deposition in rain. Also, many phosphorus fertilizers contained sulfur as impurities, which lessened the need for the application of sulfur t...