Abstract Enhancing the proton conductivity of exchange membranes (PEMs) is essential to expand applications membrane fuel cells (PEMFCs). Inspired by conduction mechanism bacteriorhodopsin, cucurbit[ n ]urils (CB[ ], where number glycoluril units, = 6, 7, or 8) are introduced into sulfonated poly(ether ether ketone) (SPEEK) matrix fabricate hybrid PEMs, employing a nature-inspired chemical engi...

Membrane separation is known as an efficient technique for the oily wastewater treatment. Therefore, in the present study, sulfonated poly (ether ether ketone) (SPEEK) was introduced into the polysulfone (PSF) solution in order to enhance the hydrophilicity and the membrane structure for the oil–water separation. The hollow fiber membranes were fabricated via a phase-inversion process. The memb...

A series of new sulfonated poly(arylene ether)s containing one sulfonic acid group, located on a pendant phenyl sulfonyl moiety, at every repeat unit was synthesized using 3-sulfonated-3’, 5’-difluorophenyl Sulfone, 4, and a variety of bisphenols. A conventional nucleophilic aromatic substitution (NAS) was utilized for the homopolymerization and copolymerization reactions. Polymerization reacti...

Novel ionomers based on polybenzimidazole block sulfonated poly(arylene ether sulfone) show excellent thermal properties. The ionic aggregation of sulfonic acid groups leads to well-developed phase separated morphology and thus high proton conductivity at wide humidity range, up to 65 mS cm(-1) at 90% relative humidity.