نتایج جستجو برای: standard free energy of adsorption
تعداد نتایج: 21296824 فیلتر نتایج به سال:
boron nitride semiconducting zigzag swcnt, $b_{cb}$$n_{cn}$$c_{1-cb-cn}$, as a potential candidate for making nanoelectronic devices was examined. in contrast to the previous dft calculations, wherein just one boron and nitrogen doping configuration have been considered, here for the average over all possible configurations, density of states (dos) was calculated in terms of boron and nitrogen ...
Oak sawdust (OSD), furniture industrial waste was chemically treated with 0.1N NaOH to give hydrolyzed oak sawdust (HOSD) which was immobilized on alginate biopolymer. Hydrolyzed oak sawdust composite (HOSDC) was utilized as low-cost adsorbent to remove basic dye (methylene blue, MB) from aqueous solution. HOSD and HOSDC were characterized by using Scanning electron microscope (SEM), thermo gra...
heavy metals such as cu(ii) and pb(ii) are among the hazardous pollutants that lead to severe ecological problems and have a toxic effect on living organisms. the removal of cu(ii) and pb(ii) by iranian bentonite experiment were conducted in single component and multi component systems. the bentonite from the birjand area was characterized by x-ray diffraction pattern and ftir spectroscopy. the...
This paper studies the corrosion inhibition of Al-Mg alloy system in 0.5 mol/dm3 NaCl solution in the presence of pyrazole derivative using potentiodynamic polarization and linear polarization method. The inhibition efficiency as a function of concentration and temperature was investigated. From the polarization curves, it can be concluded that the pyrazole derivative be...
Density-functional-based and ab initio calculations were implemented at different computational levels to estimate the binding energy of Zn2+ ion adsorbed on the available sites of a silicate MEL-type adsorbent. B3LYP and MP2 were used in combination with the 6-31G*, 6-31+G*, LanL2DZ, 6-311+G*, and Def2-TZVP basis sets. The zinc cation was found to preferentially occupy the 6MR sites followed b...
Structural parameters of raw and pre-treated viscose, modal and lyocell fibres were determined using X-ray diffraction, and compared with data obtained from iodine adsorption and tenacity measurements. A good correlation was found between iodine adsorption and structural changes. These structural parameters are correlated with surface thermodynamic parameters obtained by surface tension experim...
Surface second harmonic generation has been used to study the adsorption of alkyl phenols and anilines and their respective ions to the air/water interface. The free energies of adsorption of the neutral molecules were obtained using a simple Langmuir model. The quantitative effects of the opposing hydrophobic and solvations forces on molecular adsorption were investigated by varying the chain ...
A new activated carbon was produced from pulp and paper mill sludge as a low cost precursor via chemical activation by zinc chloride. The activated carbon was successfully used for the adsorption of phenol and two of its derivatives, i.e. 2-chlorophenol and 4-nitrophenol from aqueous solutions. The characterization of the prepared activated carbon demonstrated high textural properties for the s...
CoFe2O4 magnetic nanoparticles were modified by dopamine (DA) and ascorbic acid (AA) as anchors. Separation of the DA and AA using CoFe2O4 magnetic nanoparticles have been studied by investigating the effects of pH, concentration of the DA and AA, amount of adsorbents, contact time, ionic strength and temperature. The mechanism of adsorption was also studied. The adsorption of DA and AA to the ...
zinc (zn) is an essential micronutrient needed by plants, animals and humans. bioavailability of zn to plant root is controlled through sorption process in soils. to evaluate the effect of citric acid on zn sorption, a batch experiment was conducted with two soil samples (s1, s2), that differed in their clay and calcium carbonate contents. three levels of citric acid (0, 0.5, 1 mm) and twel...
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