Spectral confocal microscope visualizations of microsphere movement in unsaturated porous media showed that attachment at the Air Water Solid (AWS) interface was an important retention mechanism. These visualizations can aid in resolving the functional form of retention rates of colloids at the AWS interface. In this study, soil adsorption isotherm equations were adapted by replacing the chemic...

Recent experiment and simulation research on the glass forming and “jamming” materials are reviewed from the perspective of using soft colloids to establish a general picture of molecular glasses, colloids and granular materials. PACS number: 64.70.p-, 64.70pv, 64.70Q-

We report a method to prepare catalytically active Janus colloids that "swim" in fluids and describe how to determine their 3D motion using fluorescence microscopy. One commonly deployed method for catalytically active colloids to produce enhanced motion is via an asymmetrical distribution of catalyst. Here this is achieved by spin coating a dispersed layer of fluorescent polymeric colloids ont...

[1] The physics regarding the retention and mobilization of colloids in saturated and unsaturated conditions remains poorly understood, partially because of the inability to measure colloid concentrations in situ. In this study, we attached Cd ions to clay colloids and used synchrotron X rays to cause the Cd to fluoresce. By measuring the fluorescence and attenuation of the X rays we obtained s...

We study the optical response of monodisperse colloids of core-shell plasmonic nanoparticles and introduce a computational approach to optimize absorption for photothermal applications that require dilute colloids of non-interacting particles with a prescribed volume fraction. Since the volume fraction is held constant, the particle concentration is size-dependent. Optimization is achieved by c...

Aqueous solutions of ultra-pure gold nanoparticles have been prepared by methods of femtosecond laser ablation from a solid target and fragmentation from already formed colloids. Despite the absence of protecting ligands, the solutions could be (1) fairly stable and poly size-dispersed; or (2) very stable and monodispersed, for the two fabrication modalities, respectively. Fluorescence quenchin...

Lanthanide-containing nanoscale particles have been widely explored for various biomedical purposes, however, they are often prone to metal leaching. Here we have created a new coordination polymer (CP) by applying, for the first time, a stable Gd(III) chelate as building block in order to prevent any fortuitous release of free lanthanide(III) ion. The use of the Gd-DOTA-4AmP complex as a desig...

Colloid transport may facilitate off-site transport of radioactive wastes at the Hanford site, Washington State. In this study, column experiments were conducted to examine the effect of irrigation schedule on releases of in situ colloids from two Hanford sediments during saturated and unsaturated transientflow and its dependence on solution ionic strength, irrigation rate, and sediment texture...

as a third phase, thus enhancing the transport of strongly sorbing contaminants (McCarthy and Zachara, 1989). Until some two decades ago, it was believed that only the soil liquid and gaseous phases were mobile and could facilitate the transport of chemicals and nutrients through the vadose zone. It is now generally SOURCES OF MOBILE SOIL COLLOIDS accepted that also part of the soil solid phase...