The evolution of the magnetic state, crystal structure and microstructure parameters of nanocrystalline zinc-ferrite, tuned by thermal annealing of ∼4 nm nanoparticles, was systematically studied by complementary characterization methods. Structural analysis of neutron and synchrotron x-ray radiation data revealed a mixed cation distribution in the nanoparticle samples, with the degree of inver...

This work devotes to investigate synthesis and electrical properties of spinel MgCo2O4 that is considered as a candidate of the cathode materials of magnesium-ion batteries in future. Samples were synthesized by two types of techniques: solid-state reaction and wet process. The crystal structures of the samples were analyzed by X-ray diffraction, and their electrical conductivities were obtaine...

ERINGAITE-BEARING ULTRA-REFRACTORY CAI A. N. Krot, K. Nagashima, C. Ma, G. J. Wasserburg. HIGP, U. Hawai‘, USA. CalTech, USA. Introduction: Forsterite-bearing Type B (FoB) Ca,Al-rich inclusions (CAIs) are a rare type of coarse-grained igneous CAIs found almost exclusively in CV3 chondrites [1–5]. Here we describe the mineralogy, petrography, and oxygen-isotope compositions of a FoB CAI Al-2 fro...

A new solvothermal synthesis route to mixed-metal gallium oxides with the spinel structure has been developed for ternary oxides of ideal composition Ga(3-x)M(x)O(4-y) (M=Co, Zn, Ni). The structure of the novel cobalt gallate produced in this manner, Ga(1.767(8))Co(0.973(8))O(3.752(8)), has been determined from total neutron scattering to be a partially defective spinel with mixed-valent cobalt...

Nano-structure of Co–Mn spinel oxide was prepared by thermal decomposition method using [Co(NH3)4CO3]MnO4 as the precursor. The properties of the synthesized material were characterized by X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Transmission Electron Microscopy (TEM), surface area measurements, Energy-Dispersive X-ray (EDX) spectroscopy analys...

Introduction. The Wark-Lovering rims [1] found on many refractory inclusions are important recorders of nebular environments to which refractory inclusions were exposed after their formation, such as different temperature regimes and isotopic reservoirs [2]. As part of a large-scale survey of W-L rims to enable us to better understand the range of environments reflected in rims, an inclusion of...

Structure-electrochemical property correlation is presented for lithium-manganese-rich layered-layered nickel manganese cobalt oxide (LMR-NMC) having composition Li1.2Co0.1Mn0.55Ni0.15O2 (TODA HE5050) in order to examine the possible reasons for voltage fade during short-to-mid-term electrochemical cycling. The Li1.2Co0.1Mn0.55Ni0.15O2 based cathodes were cycled at two different upper cutoff vo...

Spinel has historically been one of the most highly revered gemstones. However, over an extended period of time, its popularity had suffered as a result of many factors, including its classification as “semi-precious” and a general confusion with another dominant red gemstone: ruby. More recently though, spinel has been making a strong comeback and so its popularity is once again on the rise. A...

melt fractions that percolated pervasively throughout the massif and On the basis of their structural and compositional characteristics, had a refractory, calc-alkaline character. Locally, these melts were mafic rocks in the Ronda peridotite are classified into four groups: tapped into cracks forming intrusive dykes. group A (garnet-bearing rocks) occurring in the spinel tectonite domain; group...

Li-rich layered Li1+xMnyM1-x-yO2 (or denoted xLi2MnO3·(1 -x)LiMO2, M = Ni, Co, Mn, etc.) are promising cathode materials for high energy-density Li-ion batteries. However, their commercial applications suffer from problems such as a drop in the capacity and discharge voltage during cycling. In this work, the cycling performance of a layered oxide Li1.2Ni0.13Co0.13Mn0.54O2 is improved by integra...