A mathematical model is developed to describe the contaminant transport, sorption, and biodegradation in saturated porous media. In the model development, sorption was accounted for as a kinetic process for the contaminant transport. In addition, a double Monod function was incorporated into the model to describe the biodegradation of contaminants and utilization of oxygen. In the description o...

In this work, sorption of nickel from aqueous solution on hypnea valentiae, red macro algae, was investigated. Batch experiments have been carried out to find the effect of various parameters such as pH, temperature, sorbent dosage, metal concentration and contact time on the sorption of nickel using hypnea valentiae . Response surface methodology (RSM) is employed to optimize the process param...

This study reports the distribution coefficient between phospholipid bilayer membranes and phosphate buffered saline (PBS) medium (DMW,PBS) for 19 cationic surfactants. The method used a sorbent dilution series with solid supported lipid membranes (SSLMs). The existing SSLM protocol, applying a 96 well plate setup, was adapted to use 1.5 mL glass autosampler vials instead, which facilitated sam...

The increased use of veterinary antibiotics in modern agriculture for therapeutic uses and growth promotion has raised concern regarding the environmental impacts of antibiotic residues in soil and water. The mobility and transport of antibiotics in the environment depends on their sorption behavior, which is typically predicted by extrapolating from an experimentally determined soil-water dist...

Understanding the spatial variability of herbicide sorption to soil is important in determining the bioavailability as well as leaching potential of the chemical across a field. Multiple methods have been used to estimate herbicide sorption variability at the macroscale, but it has been difficult to measure soil heterogeneity or herbicide sorption at the individual field level. One method to de...

The sorption affinity of eighty-six charged amine structures to phospholipid monolayers (log KIAM) was determined using immobilized artificial membrane high-performance liquid chromatography (IAM-HPLC). The amine compounds covered the most prevalent types of polar groups, widely ranged in structural complexity, and included forty-seven pharmaceuticals, as well as several narcotics and pesticide...

Metal-organic frameworks are a class of crystalline porous materials with potential applications in catalysis, gas separation and storage, and so on. Of great importance is the development of innovative synthetic strategies to optimize porosity, composition and functionality to target specific applications. Here we show a platform for the development of metal-organic materials and control of th...

A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.

in this work, removal of c. i. acid red 14 was investigated by pumice stone as a low cost adsorbent. various parameters such as initial dye solution, contact time and ph were studied. removal of dye were increased by increasing of contact time and initial dye solution and deceased by increasing of ph. three isotherm models were studied. linear and non-linear regression analyses were used for de...