Chemically modified graphite is an economical material with promising applications in its own right or as an intermediate in the synthesis of graphene. However, because of its extreme chemical inertness, to date only two methods-oxidation and fluorination-have been found which can modify graphite with high yield and large throughput. Herein, we describe a third chemical approach for the synthes...

Abstract Due to their outstanding optoelectronic properties, lead-based halide perovskite materials have been applied as efficient photoactive in solution-processed solar cells. Current record efficiencies offer the promise surpass those of silicon However, uncertainty about potential toxicity and facile dissolution water requires a search for new alternative perovskite-like materials. Thanks f...

Abstract There is currently substantial interest in commercializing perovskite solar cells as they offer superior properties over silicon-based cells, such ability for bandgap tuning, higher absorption coefficients, and potentially lower manufacturing costs. However, trap states originating from ionic vacancies, imperfect interfaces, grain boundaries have hampered their performance long-term st...

The radiation-sensitive nature of halide perovskites has hindered structural studies at the atomic scale. We overcome this obstacle by applying low dose-rate in-line holography, which combines aberration-corrected high-resolution transmission electron microscopy with exit-wave reconstruction. This technique successfully yields the genuine atomic structure of ultrathin two-dimensional CsPbBr3 ha...

Peroxidase, H2O2, and a halide form a powerful antimicrobial system in phagocytes and tissue fluids, and certain microorganisms can serve as the source of H2O2 for this system. H2O2-generating Lactobacillus acidophilus (LB+) is present in the vagina of most normal women and peroxidase has been detected in vaginal fluid. LB+ at high concentration is viricidal to HIV-1, and, at levels where LB+ i...

Many nickel-based catalysts have been reported for cross-coupling reactions of nonactivated alkyl halides. The mechanistic understanding of these reactions is still primitive. Here we report a mechanistic study of alkyl-alkyl Kumada coupling catalyzed by a preformed nickel(II) pincer complex ([(N2N)Ni-Cl]). The coupling proceeds through a radical process, involving two nickel centers for the ox...

Abstract To reach the target of carbon neutral, a transition from fossil energy to renewable is unavoidable. Photovoltaic technology considered one most prominent sources energy. Recently, metal halide perovskite materials have attracted tremendous interest in areas optoelectronic devices due their ease processing and outstanding performance. date, solar cells (PSCs) shown high power conversion...

Density-functional theory and second order Møller-Plesset perturbation theory calculations indicate that halogen atoms bond preferentially to halide substrate atoms on a series of alkali halide surfaces, rather than to the alkali atoms as might be anticipated. An analysis of the electronic structures in each system reveals that this novel adsorption mode is stabilized by the formation of textbo...

the water deficit is the most important limiting non-biological factor to achieve the potential yield of crops. to evaluate the effect of silicon application on yield of millet under drought stress in field an experimental was carried out. treatments were included three irrigation regimes after 60 (non-stress), 90 (moderate stress) and 120 (severe stress) mm evaporation from evaporation pan, cl...

Monodispersed CdS nanocrystals with controllable shape and phase have been successfully synthesized in this study by adding cationic surfactant in noninjection synthesis system. With the increase of the amount of cetyltrimethylammonium chloride (CTAC) added, the shape of the CdS nanocrystals changed from spherical to multi-armed, and the phase changed from zinc-blende to wurtzite. It was found ...