highly self-ordered alumina nanopore arrays were fabricated using hard anodization technique in different mixtures of oxalic/phosphoric acid. the phosphoric acid concentration was varied from 0.05 to 0.3 m while the oxalic acid concentration was changed between 0.3 and 0.4 m. the self ordered nanoporous arrays were obtained in anodization voltage changing from 130 to 200 v. the interpore distan...

sulfonic acid-based precursors (sap) play an important role in tailoring mesoporous silica’s and convert them to a solid acid catalyst with a bronsted-type nature. these kinds of solid acids contribute to sustainable and green chemistry by their heterogeneous, recyclable, and high efficiency features. therefore, knowing the properties and reactivity of saps can guide us to manufacture a sulfona...

Phosphoric acid added L-alanine (PLA) single crystals were grown successfully by slow evaporation technique at room temperature by taking 2:1 molar ratio of L-alanine and phosphoric acid. Solubility and nucleation kinetic measurements were carried out for the PLA sample. Critical nucleation parameters have been calculated. Structural analysis reveals that PLA crystal crystallizes in orthorhombi...

Abstract Mefenamic acid is a nonsteroidal anti-inflammatory drug (NSAID) that has analgesic,anti-infammatory and antipyretic actions. It is used to relieve mild to moderate pains. Solid-phase extraction of mefenamic acid by a polymer grafted to silica gel is reported . Poly allyl glycidyl ether/iminodiacetic acid-co-N, N-dimethylacrylamide was synthesized and grafted to silica gel and was used ...

nano silica sulfuric acid as a solid acid, was described to be an effective catalyst for one-pot three-component reaction of kojic acid, aryl aldehydes and indoles for the preparation of 2-substituted aryl (indolyl) kojic acid derivatives. the catalyst was prepared by combination of chlorosulfonic acid to nano silica gel. the size of nanoparticles were observed with sem.all prepared compounds w...

A highly enantioselective hydroamination/N-sulfonyliminium cyclization cascade is reported using a combination of gold(I) and chiral phosphoric acid catalysts. An initial 5-exo-dig hydroamination and a subsequent phosphoric acid catalyzed cyclization process provide access to complex sulfonamide scaffolds in excellent yield and high enantiocontrol. The method can be extended to lactam derivativ...

Phosphoric acid is an inorganic acid used for producing graphene sheets by delaminating graphite in (electro-)chemical baths. The observed phenomenology during the electrochemical treatment in phosphoric acid solution is partially different from other acidic solutions, such as sulfuric and perchloric acid solutions, where the graphite surface mainly forms blisters. In fact, the graphite surface...