In the secondary circuit of nuclear Pressurized Water Reactors, corrosion products and impurities lead to formation undesirable hard deposits, called sludge, on tube sheet steam generators. Theses deposits are mainly composed iron (magnetite), alumina silica. The sludge piles is investigated by reproducing reaction precursor oxides in conditions generator (275 °C, 58 bar). Mixtures magnetite, γ...

We report on the fabrication, the characterization, and the optical simulation of a gold-silica nanocomposite and present its integration into a broadband anti-reflective coating (ARC) for a silicon substrate. The two-layer ARC consists of a nanocomposite (randomly distributed gold cluster in a silica matrix) and a pure silica film. We capitalize on the large refractive index of the composite t...

Polyester silica nanocomposite fabrics were prepared by incorporating different concentrations of silica nano particles to the fabric by pad-dry-cure method. The prepared composite fabrics were analyzed in terms of change in their mechanical, structural as well as their functional properties. The surface morphology showed the uniform distribution of silica nano particles on fabric through SEM, ...

Synthetic approaches for new nanocomposite materials with relatively high cholinesterase activity have been developed. The peculiarity of the formation of such systems is the introduction of cholinesterase into polymer with subsequent incorporation on the ready-made silica particles and into the polysiloxane matrixes during sol-gel synthesis. Evaluation of the cholinesterase activity has been f...

in  this  work,  a  new  hybrid  organometallic-inorganic  hybrid nanomaterial was prepared by immobilization of acetyl ferrocene on the  surface  of magnetite  nanoparticles. covalent  grafting of silica coated magnetite nanoparticles (scmnps) with 3-aminopropyl triethoxysilane gave aminopropyl-modified magnetite nanoparticles (ampscmnps). then, schiff base condensation  of ampscmnps with acet...

Mesostructured silica-block copolymer thin films are demonstrated to provide orientationally ordered host matrixes for stable alignment of coassembled porphyrin J-aggregates with anisotropic optical properties. Visible light at 490 nm was absorbed anisotropically (A|/A⊥ ) 1.35) by aligned, hexagonally ordered (ethylene oxide)20-(propylene oxide)70-(ethylene oxide)20 (P123) triblock copolymer/si...

The ion-transport properties of composite electrolytes composed of oligomers of poly~ethylene glycol! dimethyl ether, hydrophobic fumed silica, and Li~CF3SO2)2N ~LiTFSI! are investigated using nuclear magnetic resonance ~NMR!, electrophoretic NMR ~ENMR!, ac impedance spectroscopy, and rheology. The effects of fumed silica and salt concentration on ionic conductivity, diffusivity of ions and oli...

A lyotropic AgNO3, HAuCl4 and H2PtCl6–silica liquid crystalline (LC) phase is used as a supramolecular template for a one-pot synthesis of novel noble metal or complex ion containing nanocomposite materials in the form of a film and monolith. In these structures, Ag, AuCl4 2 and PtCl6 22 ions interact with the head group of an oligo(ethylene oxide) type non-ionic surfactant (C12H25(CH2CH2O)10OH...