OBJECTIVES This study investigated the shear bond strength (SBS) and the tensile bond strength (TBS) of the zirconia-to-resin interface using different cement bonding concepts. METHODS Coplanar zirconia specimens were bonded to CoCr-cylinders measuring 5 mm in diameter and 3 mm in height. All bonding areas were first sandblasted with 110 μm Al(2)O(3) (0.28 MPa, 10 s). SBS and TBS were determi...

The aim of the present study was undertaken to investigate the effects of several surface modi cation methods applied to lithium disilicate glass ceramics (LDCs) on their bonding durability with resin-based cement. The LDC specimens were sectioned using a low-speed diamond cutting machine, crystallized by heating in a furnace, and then subjected to several surface modi cation treatments such as...

Tribological properties of composites of low density polyethylene (LDPE) reinforced with 1, 5, 10, 20 wt% micrometric Boehmite (B) and/or preheated Boehmite (HB) powders were studied in combination with two silane coupling agents (SCAs): vinyltri(2-methoxyethoxy)silane (VTMES)-SCA 972 and 3-(trimethoxysilyl)-propylmethacrylate (3MPS)-SCA 989. When coupling agents are used, the samples not subje...

AIM To compare the effect of different chemical solvents on glass fiber reinforced posts and to study the effect of these solvents on the shear bond strength of glass fiber reinforced post to core material. MATERIALS AND METHODS This study was conducted to evaluate the effect of three chemical solvents, i.e. silane coupling agent, 6% H2O2 and 37% phosphoric acid on the shear bond strength of ...

Fatigue life, morphological studies, and thermal aging properties of rattan powder-filled natural rubber (NR) composites were investigated as a function of filler loading and a silane coupling agent. NR composites were prepared by the incorporation of rattan powder in the range of 0 to 30 phr into a NR matrix with a laboratory size two roll mill. Thermal aging was carried out for 7 and 14 days ...

Hybrid nanomaterials based on zinc oxide were synthesized via the sol-gel method, using different silane coupling agents: (3-glycidyloxypropyl)trimethoxysilane (GPTMS), phenyltriethoxysilane (PhTES), octyltriethoxysilane (OTES), and octadecyltriethoxysilane (ODTES). Morphological properties and the silane precursor type effect on the particle size were investigated using dynamic light scatterin...

Unmodified Fe(3)O(4) nanoparticles do not stabilize Pickering emulsions of a polar oil like butyl butyrate. In order to obtain stable emulsions, the Fe(3)O(4) nanoparticles were modified by either carboxylic acid (RCOOH) or silane coupling agents (RSi(OC(2)H(5))(3)) to increase their hydrophobicity. The influence of such surface modification on the stability of the resultant Pickering emulsions...

The aim of this study was to determine the optimum silane-coupling agent and the optimum concentration of acid agent when bonding to porcelain surfaces. Eighty deglazed feldspathic porcelain discs with a diameter of 10 mm and a thickness of 2 mm mounted in acrylic resin blocks were randomly divided into four groups. In groups 1 and 2, the porcelain surfaces were etched with 9.6 per cent hydrofl...

The present study attempts to incorporate methacrylate-based polymers into ordered lamellar organic/inorganic nanocomposite films composed of alternating SiO2/polymer layers. The films are prepared by dip-coating from a solution containing the monomers and silica precursors, thus leading to composite lamellar mesostructured materials through evaporation-induced self-assembly (EISA). A polymeriz...

Experimental design and response surface methodology (RSM) were used to optimize the modification of conditions for glass surface grafting with acrylamide (AM) monomer for preparation of a glass fiber reinforced poly(vinylidene fluoride) (PVDF) composite membrane (GFRP-CM). The factors considered for experimental design were the UV (ultraviolet)-irradiation time, the concentrations of the initi...