Mode coupling theory (MCT) appears to explain several, though not all, aspects of the glass transition in colloids (particularly when short-range attractions are present). Developments of MCT, from rational foundations in statistical mechanics, account qualitatively for nonlinear flow behaviour such as the yield stress of a hard-sphere colloidal glass. Such theories so far only predict shear th...

The non-Newtonian shear rheology of colloidal dispersions is the result of the competition and balance between hydrodynamic (dissipative) and thermodynamic (conservative) forces that lead to a nonequilibrium microstructure under flow. We present the first experimental measurements of the shear induced microstructure of a concentrated, near hard-sphere colloidal dispersion through the shear thic...

The rheology and shear-induced structures of a series of self-assembled surfactant worm-like micelles (WLMs) with varying levels of branching are measured using rheoand flow-small angle neutron scattering (SANS). The degree of branching in the mixed cationic/anionic surfactant (CTAT/SDBS) WLMs is controlled via the addition of the hydrotropic salt sodium tosylate and verified by cryo-TEM. The l...