The synthesis of poly-1,3-bisdiphenylene-2-phenyl allyl (BDPA) radicals via a new anionic oligomerization strategy is reported. The material displays a reversible reduction from the orange-red radical to the blue carbanion in solution.

Heterodisulfide reductase (HDR) from methanogenic archaea is an iron-sulfur protein that catalyzes reversible reduction of the heterodisulfide (CoM-S-S-CoB) of the methanogenic thiol-coenzymes, coenzyme M (CoM-SH) and coenzyme B (CoB-SH). Via the characterization of a paramagnetic reaction intermediate generated upon oxidation of the enzyme in the presence of coenzyme M, the enzyme was shown to...

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posterior reversible encephalopathy syndrome (pres) is associated with various clinical manifestations such as headache, blurred vision, confusion and tonic-clonic convulsion. some of the predisposing factors for pres include hypertensive encephalopathy, preeclampsia and eclampsia, lupus erythematosus, thrombotic thrombocytopenic purpura and long-term use of immunosuppressive drugs. this condit...

various synthesis methods have been proposed in the literature for reversible and quantum logic circuits. however, there are few algorithms to optimize an existing circuit with multiple constraints simultaneously. in this paper, some heuristics in genetic algorithms (ga) to optimize a given circuit in terms of quantum cost, number of gates, location of garbage outputs, and delay, are proposed. ...

The voltammetric characteristics of bismuth(III)-oxinate in chloroform at the mercury electrode were investigated and a quasi-reversible behavior for Bi(III) oxinate reduction was confirmed. Preceded by the extraction of Bi(III) oxinate in chloroform, differential pulse polarography was developed in the extracts for determination of the trace-bismuth. The linear range of the calibration gra...

Mo/W formate dehydrogenases catalyze the reversible reduction of CO2 species to formate. It is thought that substrate and not a hydrated like HCO3?, but there still no indisputable evidence for this, in spite extreme importance nature mechanistic studies. We devised simple electrochemical method definitively demonstrate indeed CO2.

PUSH-PULL MOLECULES: MODELS AND POLYMER BUILDING BLOCKS FOR ORGANIC PHOTOVOLTAIC APPLICATIONS FEBRUARY 2014 RAYMOND DEVAUGHN, B.S., UNIVERSITY OF THE DISTRICT OF COLUMBIA M.S., UNIVERSITY OF MASSACHUSETTS AMHERST Directed by: Professor Paul M. Lahti Several fluorenone alkynyl based oligo conjugated molecules were synthesized and characterized. Most compounds exhibited UV---Vis absorption onset ...

Previous reports from this laboratory have described the isolation of 6-hydroxynicotinic acid and 6-0x0-1 ,4,5,6-tetrahydronicotinic acid from the reaction media of a clostridial species grown on nicotinic acid (1). Bn enzyme that catalyzes the reversible oxidation of nicotinic acid to HNA’ has been purified from extracts of this microorganism (2). Since fortified crude extract of this Clostrid...