The production of over 400 grams of pure gadolinium metal by reduction of the anhydrous chloride by calcium in tantalum vessels is described; yields were over 97%. The use of the same techniques in an attempt to prepare yttrium metal were partially successful.

the mass transfer performance of a pulsed disc and doughnut column for extraction of samarium and gadolinium from aqueous nitrate solution with d2ehpa was investigated. the effects of operating parameters such as pulsation intensity, continuous and dispersed phase velocities on column performance were investigated. the axial dispersion model was used to obtain the overall mass transfer coeffici...

The semiempirical theories of mixtures developed by van Laar, Margules, Scatchard-Hamer, Wilson and Renon and Prausnitz are used to study the concentration fluctuations of binary liquid alloys formed among the alkali metals. Examination of the fitting capabilities of these theories leads to the conclusion that those of van Laar, Scatchard-Hamer and Renon and Prausnitz are appropriate both when ...

Aquatic sediments contaminated with heavy metals originating from mining and metallurgical activities pose significant risk to the environment and human health. These sediments not only act as a sink for heavy metals, but can also constitute a secondary source of heavy metal contamination. A variety of sorbent materials has demonstrated the potential to immobilize heavy metals. However, the com...

The ability of dead cells of endophytic Drechslera hawaiiensis of Morus alba L. grown in heavy metals habitats for bioremoval of cadmium (Cd2+), copper (Cu2+), and lead (Pb2+) in aqueous solution was evaluated under different conditions. Whereas the highest extent of Cd2+ and Cu2+ removal and uptake occurred at pH 8 as well as Pb2+ occurred at neutral pH (6-7) after equilibrium time 10 min. Ini...