In the present study, impact of shrinkage on pyrolysis of biomass particles is studied employing a kinetic model coupled with heat transfer model using a practically significant kinetic scheme consisting of physically measurable parameters. The numerical model is used to examine the impact of shrinkage on temperature profile and pyrolysis conversion time considering cylindrical geometry. Finite...

This review on the formation of polyaromatic hydrocarbons (PAH) and dioxins during biomass fast pyrolysis was funded by the Washington State Department of Ecology. It includes a worldwide literature review of what is known and not known about this timely area. Areas needing further research and development work are identified and, as such, serve as a base for further work. For example, the need...

Pyrolyzing biosolids can decrease volume and increase value of solids while anaerobic digestion gas liquids from the process could overall methane production. Prediction behavior biogas yield through simulation is valuable when considering new substrates for digestion. In this study, pyrolysis were implemented in Anaerobic Digestion Model No 1 (ADM1) together with a stream thermally hydrolyzed ...

Western Research Institute is developing a new pyrolysis process called ROPE© (Recycle Oil Pyrolysis and Extraction) for recovering products from tar sands that require a minimum of upgrading to produce finished, marketable fuels or that can be used as a diluent to decrease the pour point of bitumen for transportation. The concept consists of two pyrolysis steps: (1) retorting tar sand at a low...

A combined pyrolysis and gasification process for sewage sludge was studied in this paper for the purpose of its safe disposal with energy self-balance. Three sewage sludge samples with different dry basis lower heat values (LHV(db)) were used to evaluate the constraints on this combined process. Those samples were pre-dried and then pyrolysed within the temperature range of 400-550 degrees C. ...

Two types of silicon carbide fibers with sinusoidal electrical resistivity were prepared by using different pyrolysis technology. The relationship between the microstructure and the electrical resistivity of these fibers was investigated and compared. The results indicated that carbon layer was the main conductive phase in the SiC fibers obtained by means of one step pyrolysis, whereas a free c...

A new technique was proposed to co-produce phenol and activated carbon (AC) from catalytic fast pyrolysis of biomass impregnated with K3PO4 in a hydrogen atmosphere, followed by activation of the pyrolytic solid residues. Lab-scale catalytic fast pyrolysis experiments were performed to quantitatively determine the pyrolytic product distribution, as well as to investigate the effects of several ...

The thermogravimetric characteristics of wheat straw EMAL (Enzymatic Acidolysis Lignin) were analyzed. The effect of the heating rates on the thermogravimetric characteristics of wheat straw and the wheat straw influence on pyrolysis were investigated. The influence of various heating rates on wheat straw was significant, the pyrolysis rate of wheat straw EMAL increased at temperatures between ...

Thermochemical processing methods such as pyrolysis are of growing interest as a means of converting biomass into fuels and commodity chemicals in a sustainable manner. Macroalgae, or seaweed, represent a novel class of feedstock for pyrolysis that, owing to the nature of the environments in which they grow coupled with their biochemistry, naturally possess high metal contents. Although the imp...

Biomass is of growing interest as a secondary energy source. Biomass could be converted to energy especially by pyrolysis or gasification. Understanding the mechanism and the kinetics of biomass pyrolysis and gasification could be the key to the design of industrial devices capable of processing vast amounts of biomass feedstock. There are multiple reactions describing the decomposition of biom...