In this study, we conducted a series of polymerization studies hexyl methacrylate in dimethyl sulfoxide with (0.1 - 0.4) mol dm-3 monomer and (1 10-3 – 4 10-3) benzoyl peroxide as initiators at 70 °C. Using the well-known conversion vs. time technique, effects initiator concentration on rate (Rp) were studied. An order 0.35 was obtained accordance theory divergence from normal kinetics detected...