ion of the proton from the amino group of the monomer (phenyl 4-(alkylamino)benzoate) by the base, the reactivity of the phenyl ester moiety is deactivated, which prevents monomers from reacting with each other. The anion produced by proton abstraction from the monomer will only react with initiator, leading to an activated monomer that possesses a more reactive phenyl ester moiety compared to ...

Previous studies suggested that y87 Gln in hemoglobin (Hb) F is an important site for promoting inhibition of Hb S (cy#: polymerization by H b F. We engineered and isolated the double mutant ) using a yeast expression system and characterized polymerization properties of this modified tetramer in an effort to clarify the role of Gln at position 87 in inhibiting H b S polymerization. Electrop...

INTRODUCTION Emulsion polymerization yielding polymer latexes, is carried out on a vast scale. The use of water as a dispersion medium offers a unique combination of features, such as effective heat transfer, effective stabilization of polymer particles by surfactants, and environmental friendliness. By contrast to polymerization in solution or in the bulk, in emulsion polymerization a large po...

The coordination polymerization of ethylene in water as a reaction medium was studied. Rubbery amorphous branched polyethylene was obtained when a known cationic diimine-substituted methyl complex was employed as a catalyst precursor. High rates of up to 900 TOh(-1) (turnover frequency) were observed. In contrast to solution polymerization in an organic solvent, the rate of suspension polymeriz...

Objective: Bulk-fill composites are a group of composite resins designed for easy and fast filling of large cavities. This study aimed to assess the color stability of bulk-fill composites subjected to xenon radiation and evaluate their color change (&DeltaE) following polymerization. Methods: In this in vitro experimental study, 30 specimens (4mm in height and 8mm in diameter) were fabricat...

Photo-controlled atom transfer radical polymerization (PhotoATRP) was implemented, for the first time, to accomplish polymerization-induced self-assembly (PISA) mediated by UV light (? = 365 nm) us...

The SCAR/WAVE complex controls actin polymerization at the leading edges of moving cells, but its mechanism of regulation remains unclear. The recent determination of its crystal structure, and identification of the binding sites for upstream regulators, mean its workings can finally start to be revealed.

Recent studies have provided important new insights into the forces exerted by actin polymerization during Listeria motility. The results also expose deficiencies in our understanding of this process, and suggest future directions for complete understanding of the molecular mechanisms involved.

Polymerization conditions in the Pickering emulsion of colloidal silica-stabilized polystyrene latex were optimized. The influence process on various parameters, including particle size and distribution was investigated. Monomodal particles obtained by conducting at a temperature 80°C slightly acidic environment (pH = 5), while maintaining fast monomer conversion. It has been shown that amount ...