This paper reports a stimuli-responsive designer supramolecular polymer gel in dimethylsulphoxide (DMSO)/water (1:2) based on dipeptide amphiphile and β-cyclodextrin (β-CD) The contains caproic acid at the N terminus methyl ester C terminus. From X-ray single crystal diffraction, adopts kink-like conformation. self-assembled to form parallel sheet-like structure stabilized by multiple intermole...

We introduce a comprehensive model of a mucin-like polyelectrolyte gel swelling-deswelling which includes the ion-mediated crosslinking of polymer strands and the exchange of divalent and monovalent ions in the gel. The gel is modeled as a multi-phase mixture which accounts for the polymer and solvent volume fractions and velocities as well as ionic species concentrations. Motion is determined ...

The phase behavior of model athermal silica ~radius R550 nm!–polystyrene–toluene suspensions has been determined over nearly two orders of magnitude in polymer or colloid size asymmetry. Fluid–gel, fluid–crystal, and fluid–fluid transitions are observed as Rg , the polymer radius of gyration, increases. Based on the polymer concentration relative to the dilute–semidilute crossover density, cp /...

The cell is rich with biopolymeric surfaces. Yet, the role of these surfaces and attendant surface-water interfaces has received little attention among biologists, most of whom consider water as a neutral carrier. This review aims to begin bridging the gap between biology and interface science-to show that a surface-oriented approach has power to bring fresh insights into an otherwise impenetra...

In this study, xanthan gum-facilitated ethyl cellulose microsponges were prepared by the double emulsification technique and subsequently dispersed in a carbopol gel base for controlled delivery of diclofenac sodium to the skin. Scanning electron microscopy revealed the porous, spherical nature of the microsponges. Increase in the drug/polymer ratio (0.4:1, 0.6:1, 0.8:1, m/m) increased their yi...