Present study report on biodegradation of starch grafted polyethylene (PE), successfully synthesized by graft copolymerization method using benzoyl peroxide as the radical initiator. Biodegradable behavior of the grafted PE was ascertained by soil burial test. Percent weight loss was measured as a function of number of days and observed that it increased with increasing number of days. Microana...

The effect of short-chain branching (SCB) on the persistence length lp of polyethylene (PE) was studied using small-angle neutron scattering (SANS). In thermodynamically good solvents, lp can be measured directly from the scattering vector qtr at the crossover from good solvent mass-fractal scaling to the rodlike persistent scaling, using the unified equation described in the text. The method w...

Novel polymeric active food packaging films comprising halloysite nanotubes (HNTs) as active agents were developed. HNTs which are hollow tubular clay nanoparticles were utilized as nanofillers absorbing the naturally produced ethylene gas that causes softening and aging of fruits and vegetables; at the same time, limiting the migration of spoilage-inducing gas molecules within the polymer matr...

The authors studied the availability of parenteral solutions of diazepam in glass bottles or polyethylene (PE) containers during infusion through polyvinyl chloride (PVC) administration sets. Diazepam solutions in concentration of 1000 mg/500 ml in 0.9% sodium chloride (NS) and 5% glucose (G5W) injection were infused at a flow rate of 30 ml/h, and samples were taken from the bottle and at the e...

The structure and dynamics of linear monodisperse polyethylene (PE) melts (C160H322 and C440H882) containing homogeneously distributed spherical nanoparticles were investigated. The PE chains were simulated using a coarse-grained model and a Monte Carlo algorithm. Two variables were considered: (i) the wall-to-wall distance between particles d and (ii) the interaction energy between monomers an...

Combining extensional rheology with in-situ synchrotron ultrafast x-ray scattering, we studied flow-induced phase behaviors of polyethylene (PE) in a wide temperature range up to 240 °C. Non-equilibrium phase diagrams of crystallization and melting under flow conditions are constructed in stress-temperature space, composing of melt, non-crystalline δ, hexagonal and orthorhombic phases. The non-...

The asphalt paver must fulfill a set of basic requirements, from sufficient bearing capacity for the expected loads, stability and good resistance to deformations resulting passage large loads at high temperatures, also securing an impermeable surface that achieves adequate drainage water. Hence, it is necessary search permanently continuously improved materials are resistant influence factors ...

This work demonstrates how the addition of few-layer graphene (FLG) influences processability and mechanical properties mixed polyolefin waste stream (R-(PE/PP)). Three different types compounds were investigated: (1) R-(PE/PP) with FLG; (2) blends prime polyethylene (PE) or polypropylene (PP) PP copolymer; (3) both polymer FLG. The was assessed by measuring torque during melt extrusion, flow i...

Crystallization-driven self-assembly of polyethylene-b-poly(tert-butylacrylate) (PE-b-PtBA) block copolymers (BCPs) in N,N-dimethyl formamide (DMF) was studied. It is found that all three PE-b-PtBA BCPs used in this work can self-assemble into one-dimensional crystalline cylindrical micelles. When the BCP solution is cooled to crystallization temperature (Tc) from 130 °C, the seed micelles may ...

Oxidative degradation of ultra-high molecular weight polyethylene (UHMWPE; PE), due to gamma irradiation sterilization in air, increases wear rate in artificial joint. Not only adhesive and abrasive wear but also delamination (flaking), a typical wear of the PE component in artificial knee joint, and fracture could be observed. This paper deals with gamma-irradiation effects on severe wear mech...