We report the first use of cobalt aluminophosphate (CoAPO5) as a water oxidation catalyst. A decrease in the overvoltage by about 0.2 V with respect to catalyst free FTO has been observed. Additionally, we show that CoAPO5, deposited on ITO or Pt, can also act as a photo-electro-catalyst, as it generates enhanced oxidation currents in the presence of light starting from a bias of +0.8 V vs. Ag/...

The photo-oxidation process by combination of UV light and H20 2 generates hydroxyl radicals which are capable of oxidising many organic compounds which are refractory type and difficult to oxidize by conve nt ional' chemical treatment. In the present study, photo-oxidation of Direct Yellow 12 (DY 12) dye has been carri ed out in an annular type photoreactor using 8 Watt low pressure mercury la...

The endocytotic pathway involves a complex, dynamic and interacting system of intracellular compartments. PKH26 is a fluorescent dye specific for long-lasting cell membrane labelling which has been successfully used for investigating cell internalization processes, at either flow cytometry or fluorescence microscopy. In the present work, diaminobenzidine photo-oxidation was tested as a procedur...

Isoprene is globally the most ubiquitous nonmethane hydrocarbon. The biogenic emission is found in abundance and has a propensity for SOA formation in diverse climates. It is important to characterize isoprene SOA formation with varying reaction temperature. In this work, the effect of temperature on SOA formation, physical properties, and chemical nature is probed. Three experimental systems a...

A readily accessible iridium(iii) phenyl-tetrazole complex ([Ir(ptrz)2(tBu-bpy)]+, 2; Hptrz = 2-methyl-5-phenyl-tetrazole; tBu-bpy = 4,4'-di-tert-butyl-2,2'-bipyridine) is shown to be a versatile catalyst for a new photocatalytic Michael reaction. Under light irradiation in the presence of 2, a dithiane 2-carboxylic acid, obtained by simple hydrolysis of a commercially available ethyl ester, ge...

We report a synergistic effect involving hydrogenation and nitridation cotreatment of TiO(2) nanowire (NW) arrays that improves the water photo-oxidation performance under visible light illumination. The visible light (>420 nm) photocurrent of the cotreated TiO(2) is 0.16 mA/cm(2) and accounts for 41% of the total photocurrent under simulated AM 1.5 G illumination. Electron paramagnetic resonan...

Textile industries have their own importance in Indian economy. It consumes large amount of water and as a result huge amount of waste water is generated. Textile effluent comprises of suspended solids, mineral oils, residual oils and is characterized by high BOD (from 700 to 2000 mg/l) and COD loads. It is necessary to treat the waste water so that it does not have any threat to the environmen...

Wastewaters from textile industry contain various pollutants including a high content of organic matter, surfactants, additives and dyes. Dyes have obtained notoriety as hazardous substances, because most of them are toxic and considered to be resistant to biodegradation. Recently, advanced oxidation processes (AOP) have received considerable attention because it is possible to degrade organic ...

In this study, we applied cluster beam deposition (CBD) as a new approach for fabricating efficient plasmon-based photocatalytic materials. Au nanoclusters (AuNCs) produced in the gas phase were deposited on TiO₂ P25-coated silicon wafers with coverage ranging from 2 to 8 atomic monolayer (ML) equivalents. Scanning Electron Microscopy (SEM) images of the AuNCs modified TiO₂ P25 films show that ...

A mutant inbred line of Zea mays L. (M11) in which chlorophyll accumulation is particularly sensitive to low temperature is described. Under natural light conditions the chlorophyll content of seedlings is negligible below 17 degrees but is normal at high temperature. Seedlings of M11 can synthesize chloroplast pigments at 16 degrees but at a rate slower than normal. When photo-oxidation is min...