The supercritical extraction process is a technique that has increasingly been applied in various industries recent years. Solubility determination the region key feature for this process. However, high expenses and time consuming experiments task obligates need modeling. In study, thermodynamic model proposed to correlate solubility of solid hydrocarbons, namely, 1-hexadecanol, 1-octadecanol, ...

A continuous flow apparatus was applied to measure the phase equilibrium at 523 K and 573 K. The performance of analysed with determination vapor pressures water temperatures ( T = 453 473 K). measured deviated from literature values less than 1 %. Vapor n -dodecane, -hexadecane phenol were 523–623 K) and, bubble point -dodecane + pure components compared values. Relative pressure value 2 % for...

In the present work, we develop a predictive corresponding-states correlation for the binary interaction parameters of systems composed of hydrocarbons (HC), up to C10, with CO2 and H2S. Experimental data were collected from the literature for 12 HC/CO2 systems (1017 data points for 90 isotherms), 7 HC/H2S systems (293 data points for 27 isotherms), and the CO2/H2S systems (61 data points for 1...

ThermoData Engine (TDE) is the first full-scale software implementation of the dynamic data evaluation concept, as reported recently in this journal. The present paper describes two major software enhancements to TDE: (1) generation of equation of state (EOS) representations on demand and (2) establishment of a dynamically updated experimental data resource for use in the critical evaluation pr...

A new method for estimating the cubic of equation of state parameters for both pure and mixture fluids without using critical properties is proposed. In this method, the solvation charging free energy and the solvation cavity are used to determine the temperature-dependent energy parameter a(T) and volume parameter b. This method requires only element specific parameters (3 parameters for each ...

The leakage process simulation of a Natural Gas Liquid (NGL) storage tank requires the simultaneous solution of the NGL’s pressure, temperature and phase state in the tank and across the leak hole. The methods available in the literature rarely consider the liquid/vapor phase transition of the NGL during such a process. This paper provides a comprehensive pressure-temperature-phase state method...

Experimental data of methane adsorption on two types of activated carbon have been carried out at pressures up to 35 bar and at ambient temperature. Adsorption equilibrium and kinetics data at high pressure were measured using a volumetric method. A theoretical model has been presented to calculate the amount of adsorbed gas on adsorbents in a cylindrical tank. In the model, gas enters the bed ...

Steam distillation as one of the important mechanisms has a great role in oil recovery in thermal methods and so it is important to simulate this process experimentally and theoretically. In this work, the simulation of steam distillation is performed on sixteen sets of crude oil data found in the literature. Artificial intelligence (AI) tools such as artificial neural network (ANN) and also ad...

• We develop HLLC-type schemes for flow in ducts of variable cross-sectional area. The are developed general equations state. For two-phase simulations, the homogeneous equilibrium model is employed. tested on Riemann problems ideal gas and CO 2 . Including non-conservative term solver wave structure most robust. In this work, Harten-Lax-van Leer Contact (HLLC) approximate extended to through w...

In this paper, we calculate the second virial coefficient for binary mixtures of Ar with CH4 and CO in order to evaluate the performance of equations of state (EOSs). The investigated EOSs are van der Waals (vdW), Redlich-Kwong (RK), Peng-Robinson (PR), Carnahan-Starling–van der Waals (CS-vdW) and Guggenheim-van der Waals (G-vdW) based on van der Waals model. In our work, we also use Dieterici ...