The surface states of 3D topological insulators (TIs) exhibit a helical spin texture with spin locked at right angles with momentum. The chirality of this spin texture is expected to invert crossing the Dirac point, a property that has been experimentally observed by optical probes. Here, we directly determine the chirality below the Dirac point by electrically detecting spin-momentum locking i...

We develop an analytical framework for the analysis of planar chiral multi-split rings, based on a Fourier series expansion of the induced current. The number, width, and location of each split (gap) is arbitrary. Provision is made for the possibility of inserting lumped active or passive impedance loads in the gaps. The model demonstrates the hallmark of planar chirality and its consequent mag...

Features in Photoluminescence Map of SWNTs Over the past seven years photoluminescence (PL) spectroscopy has emerged as an important characterization tool for determining the (n, m) chirality and population of semiconducting SWNTs. This technique is essential for the chirality selective growth and/or the separation depending on chirality. Under excitation with the appropriate wavelength of ligh...

It is for the first time the double-twisted helical single lamellar crystals were observed in a series of synthetic chiral non-racemic main-chain liquid crystalline polyesters. Phase structure and transition behaviors were investigated. Multiple liquid crystalline phases were found including the twisted grain boundary phase. During crystallization, the chain molecules kept their memory of the p...

Chlorophylls are a fundamental class of tetrapyrroles and function as the central reaction center, accessory and photoprotective pigments in photosynthesis. Their unique individual photochemical properties are a consequence of the tetrapyrrole macrocycle, the structural chemistry and coordination behavior of the phytochlorin system, and specific substituent pattern. They achieve their full pote...

We show how extrinsic chirality, i.e. the optical activity of achiral media exhibited at oblique light incidence, can be achieved in plasmonic nanorings by symmetry breaking. We demonstrate that even a small, 5% offset of an inner hole of a 190 nm gold ring results in a measurable circular dichroism signal in the near-infrared region. By using computer simulations, we show that optical activity...

Most of the research in contemporary physical chemistry is devoted to the development of methods that extend our understanding, interpretation, and capacity to predict structural properties and dynamic behavior of molecules. The optical and magnetic spectroscopies, as well as diffraction techniques, are the principal methods for studying properties of molecules, biomolecules, and biopolymers of...

Lipid accumulation within the lumen of endolysosomal vesicles is observed in various pathologies including atherosclerosis, liver disease, neurological disorders, lysosomal storage disorders, and cancer. Current methods cannot measure lipid flux specifically within the lysosomal lumen of live cells. We developed an optical reporter, composed of a photoluminescent carbon nanotube of a single chi...

A chiral perylene diimide building block has been prepared based on an amine derivative of the amino acid L-phenylalanine. Detailed studies were carried out into the self-assembly behaviour of the material in solution and the solid state using UV/Vis, circular dichroism (CD) and fluorescence spectroscopy. For the charged building block BTPPP, the molecular chirality of the side chains is transl...

Designing metamaterials with the required band structure, topology and chirality using nano-fabrication technology revolutionises modern science impacts daily life. The approach of this work is, however, different. We take a periodic sequence, i.e., metacrystal, dissipative optical solitons rotating in single ring microresonator demonstrate its properties as electromagnetic metamaterial acting ...