For many primary storage customers, storage must balance the requirements for large capacity, high performance, and low cost. A well studied technique is to place a solid state drive (SSD) cache in front of hard disk drive (HDD) storage, which can achieve much of the performance benefit of SSDs and the cost per gigabyte efficiency of HDDs. To further lower the cost of SSD caches and increase ef...

copper (ii) phthalocyanine and 2, 9, 16, 23 tetrakis nitro copper (ii) phthalocyanine has been synthesized respectively from phthalonitrile and 4-nitro phthalonitrile under solvent-free condition using two different catalysts over nanodimensional zeolites. 4-nitro phthalonitrile synthesized from phthaimide in three steps. the newly prepared compounds have been characterized by ir, uv-vis,1h nm...

The results of this study the electrochemical transformation 3-R-4-hydroxy-1,4-dihydro-7-X-1,2,4-triazolo[5,1-c][1,2,4] obtained by voltammetry are presented. It was found that derivatives capable reduction in potential range –0.28 to –0.33 V (relative Ag/AgCl) Britton–Robinson buffer at pH = 2. behavior sodium salt 3-nitro-4-hydroxy-7-methylthio-4H-[1,2,4]triazolo[5,1-c][1,2,4]triazinide monoh...

Hydrogenase-mediated reduction of flavin mononucleotide by H 2 is exploited to enable cleaner application nitroreductase enzymes for aromatic nitro functional groups. This turns the overall reaction into a biocatalytic hydrogenation. Use flavin-containing nitroreductases in industrial biotechnology typically relies upon NADH or NADPH as reductant, together with glucose dehydrogenase and regener...

g -Aminobutiric acid (GABA), the major inhibitory neurotransmitter in the central nervous system has two major receptor subtypes (GABAA and GABAB). GABAB receptors are activated by the antispastic and muscle relaxant agent, Baclofen, which is a lipophilic derivative of GABA. Since 1962 several strategies have been reported for the synthesis of baclofen.In this study an approach has been made to...

A series of monoazo disperse dyes based on naphthalimide was synthesized using N-alkylcarboxylic acid-1,8-naphthalimide as diazo component and N,N-diethylaniline derivatives as a coupling components. 4-amino-N-ethanoic (propanoic) acid-1,8-naphthalimide was synthesized from 4-nitro-1,8-naphthalic anhydride by imidation and subsequent reduction reactions. These compounds were diazotized and furt...

We have combined the benefits of both microfluidics and flow hydrogenation to provide facile access to previously underutilized reduction and protecting group chemistries for PET imaging applications. The rapid removal of an O-benzyl protecting group to prepare 2-[(18)F]fluoroquinolin-8-ol and the reduction of a nitro group in the synthesis of 4-[(18)F]fluoroaniline were achieved within 3 minutes.

Controlling the type of indium salt and hydrosilane enables a highly selective reduction of aromatic nitro compounds into three coupling compounds, azoxybenzenes, azobenzenes and diphenylhydrazines, and one reductive compound, anilines.

Using bakers' yeast as a biocatalyst, the chemoselective reduction of aromatic nitro compounds bearing electron-withdrawing groups gave the corresponding hydroxylamines with good to excellent conversion under mild conditions.