The two title compounds, C28H26N2O2, (I), and C27H22BrClN2O2, (II), differ in their substituents, viz.4-methyl-phenyl and benzoyl rings in (I) replaced by 2-chloro-phenyl and 4- bromo-benzoyl, respectively, in (II). A significant difference between the two mol-ecules is found in the deviation of the benzoyl O atom from the least-squares plane of the ring to which it is attached [0.593 (4) and 0...

In order to study the effect of halogen bond on tautomerism in β-diketones solid-state, we have prepared a series cocrystals derived from an asymmetric β-diketone, benzoyl-4-pyridoylmethane (b4pm), as acceptor and perfluorinated iodobenzenes: iodopentaflourobenzene (ipfb), 1,2-, 1,3- 1,4-diiodotetraflorobenzene (12tfib, 13tfib 14tfib) 1,3,5-triiodo-2,4,6-trifluorobenzene (135titfb). All five ar...

C14H10O2Se2 is monoclinic, P2(1)/c. The unit-cell dimensions at 293 K are a = 12.795(2), b = 12.126(2), c = 9.0179(13)A, beta = 107.074(6)degrees, V = 1337.5(3)A3, and Z = 4. The R value is 0.048 for 2319 observed reflections. The dihedral angle between the plane C4-C7(O2)-Se1 and C9-C8(O1)-Se2 is 85.6(2)degrees, keeping the Se atom unshared electron pairs in a more stable configuration with th...

The new 2,9-dimethyl-4H-oxazolo[5’,4’:4,5]pyrano[3,2-f]quinolin-4-one was successfully prepared through the three-component iodine-catalyzed reaction of n-butyl vinyl ether with 8-amino-2-methyl-4H-chromeno[3,4-d]oxazol-4-one. latter by reduction 2-methyl-8-nitro-4H-chromeno[3,4-d]oxazol-4-one Pd/C in a hydrogen atmosphere. above nitro compound synthesized condensation N-(4-hydroxy-6-nitro-2-ox...

Alcohols 8 bearing two identical perfluoroalkyl groups were prepared by the reaction of the corresponding perfluoroalkyl phenyl ketones 7 with 0.5 equivalents of t-BuOK via Cannizzaro-type disproportionation. Utilizing the new bulky bidentate ligand with two n-C(3)F(7) groups generated from 8c, anti-apicophilic phosphorane 5a and its stable isomer 6a were synthesized. The crystal structures of ...

Reaction of substituted-aniline (8) with ethyl (l-methyl-5-nitroimidazole-2- carbonyl) acetate (9) gave 4-hydroxy-2-(l-methyl-5-nitro-2-imidazolyl)- substituted-quinolines (lo), which were converted to compound 11 with phosphorus oxychloride. Substituted-2-(l-methyl-5-nitro-2-imidazo1yl)-4.- methyl-(or phenyl-) quinolines (14) were prepared through the reaction of 2- acetyl-5-nitro-1-methy...

A new ligand {N-[(benzoyl amino)-thioxo methyl] proline} was prepared by the reaction of benzoyl isothiocyanate with proline. The ligand was characterized by FTIR, UV-Visible, and 1 HNMR.Some complexes of the ligand were synthesized and characterized on the basis of their FTIR, UV-Visible spectroscopy, conductive measurements and magnetic susceptibility. From the results obtained, the following...

In the structure of the title compound, C(14)H(12)ClNO, the N-H and C=O bonds are trans to each other. Furthermore, the C=O bond is syn to the ortho-methyl group in the benzoyl ring, similar to what is observed in 2-methyl-N-(4-methyl-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide linkage (-NHCO-) makes dihedral angles of 36.9 (7) and 46.4 (5)° with the aniline and benzoyl rings, ...