The density functional theory (DFT) calculations were used to get information concerning the interaction of curcumin with pristine and N-doped TiO2 anatase nanoparticles. Three adsorption geometries of curcumin over the TiO2 anatase nanoparticles were studied in order to fully exploit the sensing properties of TiO2 nanoparticles. Curcumin molecule adsorbs on the fivefold coordinated titanium si...

S-doped and bare mesoporous TiO2 were prepared using titanium tetraisopropoxide and thiocarbamide as raw materials. Prepared materials were characterized by means of fourier transform infrared spectroscopy FT-IR, thermogravimetry-differential scanning calorimetry (TG-DSC), X-ray diffraction (XRD), UV–Vis absorption spectroscopy, Brunauer–Emmett–Teller (BET) specific surface area and Barrett–Joy...

Hydrophilic Cu-TiO2 thin films with a gradient in the Cu concentration were prepared on glass by layer-by-layer dip-coating from TiO2 precursors. The effects of the Cu doping on the structure and properties of TiO2 self-cleaning thin films are discussed. The Cu gradient markedly affects the hydrophilicity of the films, with the water contact angle significantly reduced compared with those of th...

The adsorption of the H2S molecule on the undoped and N-doped TiO2 anatase supported Au nanoparticles were studied using density functional theory calculations. The adsorption of H2S on both Au and TiO2 sides of the nanoparticle was examined. On the TiO2 side, the fivefold coordinated titanium site was found to be the most favorable binding site, giving rise to the strong interaction of H2S wit...

We report a non-trivial facile chemical approach using ionic liquid ([bmim][Cl]) as a porogen for the synthesis of (001) faceted TiO2 nanocrystals having mesoscopic void space. This faceted TiO2 nanomaterial has been doped with Pt nanoclusters through chemical impregnation. The resulting Pt-doped TiO2 nanomaterials are thoroughly characterized by powder X-ray diffraction (PXRD), Raman spectrosc...

In this paper, MgB2 bulks were prepared with doped TiO2 nanoparticles surface-modified by 5-10% SiO2. Quantitative X-ray diffraction (XRD) analysis was performed to obtain the weight fraction of impurities using the Rietveld method. The effects of addition of TiO2/SiO2 nanoparticles on the critical temperature (Tc), the upper critical field (Hc2), and the irreversibility field (Hirr) as a funct...

In this paper, 2wt.% Fe doped TiO2 nanopowder was prepared by a combination of sol-gel and mechanical alloying methods. The mechanical alloying of Fe powder with Ti(OH)4 gel produced from the sol-gel method was used to produce Fe doped TiO2 nanopowder. The synthesized samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and diffuse reflectan...

We have successfully introduced green phosphors LaPO4:Ce, Tb (G4) or (Mg, Zn)Al11O19:Eu (G2) into TiO2 photoelectrode of dye-sensitized solar cells. The conversion efficiency of the G4-doped device was enhanced by 30% compared with the pristine TiO2 photoelectrode. The green phosphor doped at 5-wt.% ratio contributed to the reduction of resistances of the surface and interface of the photoelect...

TiO2-doped SnO2 nanopowder is synthesized via a sol-gel method and characterized by atomic force microscopy and X-ray diffraction. Using this nanopowder, we have fabricated a novel semiconductor gas sensor that is sensitive to UV light illumination. We find that gas-sensing properties of TiO2-doped SnO2 sensor can be enhanced significantly under the exposure of UV light. The sensor exhibits a h...