The quantum sieving effect between D2 and H2 is examined for a series of metal-organic frameworks (MOFs) over the temperature range 77-150 K. Isothermal adsorption measurements demonstrate a consistently larger isosteric heat of adsorption for D2 vs H2, with the largest difference being 1.4 kJ/mol in the case of Ni-MOF-74. This leads to a low-pressure selectivity for this material that increase...

Catalytic cracking of butene to propylene was carried out in a continuous-flow fixed-bed reactor over HZSM-5 catalysts modified by nickel and phosphorus. The structure and acidity of catalysts were measured by N2 adsorption, NH3-TPD and XPS. The results revealed that surface area and strong acid sites both decreased with increasing phosphorus loadings. The increment of phosphorus loadings reduc...

The adsorption characteristics of cadmium and nickel onto expanded perlite from aqueous solution have been investigated with respect to changes in pH of solution, adsorbent dosage, contact time and temperature of the solution. The maximum removal efficiency of Cd (II) is 88.8% at pH 6 and exposure to 10 g/L expanded perlite, while for Ni (II), it is 93.3% at the same pH and exposure to 8 g/L ad...

In the present study, a novel Ni(II) ion-imprinted sulfonate functionalized silica gel polymer was prepared with the surface imprinting technique by using nickel(II) as the template ion, grafted silica gel as the support, and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) and ethylene glycol dimethacrylate (EGDMA) as the functional monomer and crosslinker, respectively. The sorbent was cha...

A new biosorbent was developed by coating chitosan, a naturally and abundantly available biopolymer, on to polyvinyl chloride (PVC) beads. The biosorbent was characterized by FTIR spectra, porosity and surface area analyses. Equilibrium and column flow adsorption characteristics of copper(II) and nickel(II) ions on the biosorbent were studied. The effect of pH, agitation time, concentration of ...

A series of adsorption tests were conducted to analyze the sorption capacity of attapulgite. Ions such as cobalt, nickel, lead and cadmium were adsorbed from waste solutions onto attapulgite surface. Adsorption depletion tests were performed as a function of solid to liquid ratio, conditioning time, heavy metal ion concentration, and pH to identify the mode and extent of interactions in the sys...

In this study, the distribution coefficient of Nickel on Anarak nuclear repository was studied considering effects contaminant concentration, soil particle size, and soil/solution ratio. For purpose, two experiments were designed. The sample collected from inside trench Nuclear Repository by channel method its characteristics determined using ASTM method. batch employed while different concentr...