The title compound, [Ni(C(3)H(10)N(2))(3)][Ni(CN)(4)], is built up of [Ni(pn)(3)](2+) cations (pn is 1,2-diamino-propane) and [Ni(CN)(4)](2-) anions. Both Ni(II) atoms in the cation and the anion lie on a mirror plane. The respective ions inter-act through Coulombic forces and through a complex network of hydrogen bonds. Extended disorder associated with the cation has been resolved. The occupa...

The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal-η(3)-aza-allyl centrosymmetric complex containing two aza-allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza-allyl group are sp(2)-hybridized. The uneven Ni-C and Ni-N distances [2.045 (5)/2.060 (6) ...

— The influence of the Zn and Cd ion contents upon the natural spin resonance in Ni-Zn and Ni-Cd ferrites has been investigated. Previous experiments by other authors have shown that substituting Zn ions for Ni ions leads to a change of the total effective anisotropy field and consequently of the natural spin resonance frequency fi. ft measurements have been carried out by using a coaxial line ...

In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformyl-phenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octa-hedral coordination geometry. The two Ni atoms are bridged by two phenolate O atoms and the intra-m...

Reaction of [PPN][Fe(NO)2(SePh)2] (1) with dimeric [Ni(mu-SCH2CH2SCH2CH2S)]2 in the presence of additional NO2- produced the neutral heterobimetallic [(ON)Ni[(mu-SCH2CH2)2S]Fe(NO)2] complex (2). The X-ray crystal structures of 1 and 2 show distorted tetrahedral iron dinitrosyl groups, assigned according to the Feltham-Enemark notation as [Fe(NO)2]9 The Fe-NO bonds are off linearity by an averag...

The asymmetric unit of the title complex, [Ni(C₁₀H₈N₂)(H₂O)₄]SO₄, consists of a complex [Ni(bipy)(H₂O)₄]²⁺ cation (bipy = 2,2'-bipyridine) and a non-coordinating [SO₄]²⁻ anion. The Ni(II) atom is six-coordinated in a distorted octa-hedral geometry defined by the two N atoms of the bipy ligand and four water O atoms. The crystal structure contains extensive classical O-H⋯O hydrogen bonds, which ...

The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni-N and Ni-O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)°]. All the atoms of the meth-oxy substitutents are in the plane of the ring to which they are attached except for one which deviates sligh...

The title complex, [Ni(2)(C(4)H(8)N(4)O(2))(6)](NO(3))(4)·2CH(4)O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis-(hydroxy-meth-yl)-1,2,4-triazole ligands. The separation between the Ni(II) atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octa-hedral coordination. Inter-molecular N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds connect the ligand...

The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal-lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds connect complex and water mol-ecules to form a three-dimensional network. The O atom o...