Aluminum aminoterephthalate MOF particulate materials (NH(2)-MIL-101(Al) and NH(2)-MIL-53(Al)), studied here as components of self-detoxifying surfaces, retained their reactivity following their covalent attachment to protective surfaces utilizing a newly developed strategy in which the MOF particles were deposited on a reactive adhesive composed of polyisobutylene/toluene diisocyanate (PIB/TDI...

A new class of microporous adsorbents, the metal-organic frameworks was recently developed. Despite their promising characteristics, not much is known about their adsorption behaviour, certainly for mixtures. In this work, vapour and gas phase adsorption and separation of (i) linear and branched alkanes, cyclohexane and benzene, (ii) C8 alkylaromatic compounds and (iii) CO2 and CH4 is studied o...

The current research work reports the methods that have been developed to dope Lithium nanoparticles MIL@53-Al surface frameworks without inducing structures. prepared MOFs and Li/MIL/53-Al were characterized by XRD, TEM, SEM, BET, TGA. doped measured for hydrogen sorption capacities at 298 253 K under a pressure of 75 bar. study revealed enhanced significantly due doping lithium ions; however,...

The metal-organic framework (MOF) MIL-68(In)-NH2 was tested for dye removal from wastewater and carbon capture gas separation. synthesized as a neat, supported MOF thin film membrane spherical particles using pyridine modulator to shape the morphology. neat membranes were employed in cross-flow geometry, demonstrating strong molecular sieving. used electrospinning of poylethersulfone mixed-matr...

Optical properties, which determine the application of optical devices in different fields, are the most significant properties of optical thin films. In recent years, Metal-organic framework (MOF)-based optical thin films have attracted increasing attention because of their novel optical properties and important potential applications in optical and photoelectric devices, especially optical th...

Insight into the heat transport and water-adsorption properties of flexible MIL-53(Al) is obtained using advanced molecular dynamics simulations.

A new fluorinated member of the MIL-53(Al) family, displaying a unique temperature-induced phase transition, was synthesised via solvent-free route.