Three pH electrodes in clinical use were examined--(1) antimony electrode with remote reference electrode (Synectics 0011), (2) glass electrode with remote reference electrode (Microelectrodes Inc. MI 506) and (3) combined glass electrode with integral reference electrode (Radiometer GK2801C). In vitro studies showed that both glass electrodes were similar and superior to the antimony electrode...

a new al(iii) selective membrane based on 5-bromo(salicylidene-2-amino thiophenol) as a neutral carrier in a poly(vinyl chloride) (pvc) matrix is coated on platinum wire to determine trace amounts of al(iii) ion in various samples. the sensor exhibits a good response for al(iii) ion over a wide concentration range of 5.20 × 10-7 to 1.00 × 10-2 m  with nernstian slope of 19.64 ± 0.15 mv decade-1...

a novel modified ni-zsm-5 nanozeolite was fabricated via an organic template-free hydrothermal route. the average particle size of ni-zsm-5 nanozeolite was calculated to be 85 nm by scanning electronic microscopy. then, carbon paste electrode (cpe) was modified by ni-zsm-5 nanozeolite and ni2+ ions were then incorporated to the nanozeolite matrix. electrochemical behavior of this electrode was ...

a chemically modified carbon paste electrode with multiwall carbon nanotube (mwcnt) was prepared and used as a sensor for cu2+ ion. the unique chemical and physical properties of cnt have paved the way  to  new  and  improved  sensing  devices.  a  central  composite chemometrics  design  was  applied  for  multivariate  optimization  of the  effects  of  three  significant  parameters  (graphi...

a simple, precise, rapid and low-cost potentiometric method for diclofenac determination in pharmaceuticals is proposed. a new diclofenac-sensitive electrode was constructed by incorporating the diclofenac ion pair complex with butyl rhodamine b into graphite matrix. the electrode exhibited a linear response over the concentration range of 1 × 10-4 – 5 × 10-2 mol l-1, a detection limit of 3.9×1...

in the present study, silver oxyfluoride modified silver electrode was employed to electrocatalytic oxidation of isoniazid. the process of oxidation and its kinetics were established by using cyclic voltammetry, chronoamperometry and amperometry techniques. the modified electrode shows a stable and linear response in the concentration range of 3×10−4 to 2.1×10−3 mol l-1 with a correlation coeff...

fabrication of a cysteamine (ca) self-assembled monolayer (sam) modified gold electrode insitufunctionalized with l-lysine (lys) is presented and described. the fabricated electrode was used forhighly selective and sensitive accumulation and the determination of copper ions (cu2+) in a nanomolarconcentration. techniques like cyclic voltammetry (cv) and electrochemical impedance spectroscopy (ei...

in order to preparing strontium ion selective electrode 6-(4- nitropheny1)-2-pheny14, 4- dipropy1-3, 5-diaza-bicyclo [3, 1, 0] hex-2-ene (npdbh) was used as an ionophore. this electrode responds to sr (ii)ion with a sensitivity of 28.2 ± 0.5 mv/decade over the range 1.0 x 10-6 to 1.0 mat ph 3.0-10.0. thelimit of detection was 2.4 x 10-7 m. the influences of membrane composition, the ph of the t...

for the first time this study reported the success of using nanocrystalline hexagonal close-packed (hcp) nickel (ni) modified composite graphite (cg) electrode (hcp-nano ni/cg) for the electrocatalytic oxidation of glycerol in alkaline medium (0.1 m koh). the hcp-nano ni/cg electrode had an improve response and specificity on the electrocatalytic oxidation of glycerol over the bare cg. the elec...

in this research, a pvc membrane electrode for manganese (ii) ions based on n-(2-picolinamidoethyl)picolinamide as neutral carrier was prepared. the electrode exhibits a nemstian responseover mn(ii) concentration range of (1.0 x10-5 t01.0 x 10-1m) with a slope of 29.3±0.5 mv perdecade of concentration with a working ph range of 4.0-9.0. it has a fast response time (