A strategy for an innovative, continuous and reversible LSPR tuning using DNA origami actuation to modulate the nanometric separation of two gold nanoparticles has been developed. The actuation mechanism is based on DNA hybridization, in particular three different DNA sequences were shown to induce resonance shift of up to 6 nm.

Original and effective syntheses of crystalline silver wires and saw bundles, using reduced Keggin polyoxomolybdovanadate (POM) as mediator and reducing agent, were performed in acetonitrile at room temperature; several parameters influencing the final silver 1D-structures, with micrometric length and nanometric thickness, were varied: the nature of the POM, silver salts, vanadium(iv) source an...

A peptide was designed to generate a sub-nanometric template that guides the growth of fluorescent gold nanoclusters. The peptide was endorsed with nucleating moieties and a three-dimensional structure that arrests the growth of ultrasmall nanoparticles. The nanoclusters are not cytotoxic and can be found in the cytosol of cells.

Exposure to ozone (O3) causes reduction both in the growth and yield of rice (Oriza sativa L.). Commonly used Chlorophyll fluorescent measurements are not sensitive enough for short term exposure of O3 aiming an immediate assessments. Such a conventional method typically needs exposure over a few days to detect the influence. As an alternative method, we proposed a novel non-invasive, robust, r...

This work consists in a numerically evaluation of elastic fields distribution, caused by intrinsic dislocation networks placed at a nanometric trilayers interfaces, in order to estimate their influence on the surface topology during heterostructure operation. The organization of nanostructures is ensured by the knowledge of different elastic fields caused by buried dislocation networks and calc...

Efficient generation of anti-Stokes emission within nanometric volumes enables the design ultracompact, miniaturized photonic devices for a host applications. Many subwavelength crystals, suc...

This thesis is dedicated to the study of the magnetic properties of GaMnAs nanometric layers by the ferromagnetic resonance (FMR) technique. Three series of samples have been studied to investigate independently the influence of the strain, the hole concentration and the Mn concentration on the magnetic properties of GaMnAs. In the first series, the Ga1−xMnxAs samples with x=0.07, grown on GaAs...