Raman and IR investigations indicated the presence of reduced graphene oxide (rGO)-like residues on ceria nanoparticles after solvothermal treatment in ethanol. The appearance of such structures is closely related to cerium tert-butoxide as precursor and ethanol as solvothermal solvent. The rGO-like residues improve the catalytic CO oxidation activity. This was also confirmed by introduction of...

Levulinic acid (LA), 4-oxo-pentanoic acid, is a new platform chemical with various potential uses. In this paper, catalytic hydrogenation and oxidation of levulinic acid were studied. It was shown from experiments that levulinic acid can be hydrogenated to γ-valerolactone (GVL) over transition metal catalysts and oxidative-decarboxylated to 2-butanone (methyl-ethyl-ketone, MEK) and methyl-vinyl...

Due to the increasing use of nanometric cerium oxide in applications, concerns about the toxicity of these particles have been raised and have resulted in a large number of studies. We report here on the interactions between 7 nm anionically charged cerium oxide particles and living mammalian cells. By a modification of the particle coating including low-molecular weight ligands and polymers, t...

in this work, the characteristics of flow and heat transfer of a fluid containing nano particles of aluminum oxide with the water volume fraction (0.1-0.2-0.3)(v/v) percent of the reports. the overall heat transfer coefficient, heat transfer and the average heat transfer fluid containing nano water - aluminum oxide in a horizontal double pipe counter flow heat exchanger under turbulent flow con...

In order to reduce the operating temperature of solid oxide fuel cells (SOFCs), novel electrolyte materials based on CeO2 and BaCeO3 are being developed in the scientific realm. In this context, we propose a new methodology for preparing the nano-ceramic composite materials such as BaCe0.9Gd0.9O3-δ – Ce0.9Gd0.9O2-δ (BCGO–CGO) and BaCe0.8Sm0.2O3-δ – Ce0.8Sm0.2O2-δ (BCSO – CSO) as possible elec...

In this study, the synthesis of ceria (CeO2) nanoparticles (NPs) was examined by the biosynthesis method. Then, enzyme-like features of synthesized nanoceria were examined. Peroxidase enzyme from fig (Ficus carica) was used as a synthesis and stabilizer reagent. Furthermore, it was investigated whether the obtained nanoceria has superoxide dismutase (SOD), catalase (CAT) and peroxidase (POX) ac...

As an alternative to chromate conversion coatings, rare-earth coatings especially cerium, because of the low toxicity, have attracted considerable attention. Using dip immersion method, cerium-based conversion coating was deposited on aluminum 2024. Corrosion resistance was studied in 3.5 wt.% NaCl solution using potentiodynamic polarization, electrochemical impedance spectroscopy, and surface ...

The study on physicochemical properties of maltodextrin-coated cerium oxide nanoparticles was carried out. surface structure and CeO 2 were investigated. ability to perform the functions catalase peroxidase enzymes, as well inactivate hydroxyl radicals shown. Keywords: nanoparticles, oxide, catalytic activity, antioxidant activity.