Thin films of MnO2 are well suited for Electrochromic Photo-Voltaic (ECPV) effect and superconducting phenomenon (such as solar cells) due to its electrical and optical properties. MnO2 thin films were prepared on glass substrate using a simple and low-cost chemical spray pyrolysis technique at different substrate temperature. The MnO2 films were characterized by X-ray diffraction (XRD), transm...

The electrochemical performance and electrode reaction using AuePd nanoparticle (NP) supported mesoporous b-MnO2 as a cathode catalyst for rechargeable Lithium-Air (Li-Air) battery is reported here for the first time. In this study, AuePd NP-supported mesoporous b-MnO2 was successfully synthesized by hydrothermal process using a silica KIT-6 template. It has an initial discharge capacity of ca....

The objective of this study was to determine the effects of solution properties and light on the metal uptake and release in a nanosized, poorly crystalline manganese oxide (δ-MnO2) system. The results from synthetic water matrices revealed that the aggregation state was strongly affected by ionic strength, Ca(2+), and humic acid, and the particle aggregation subsequently changed the ability of...

Understanding the fundamentals of arsenic adsorption and oxidation reactions is critical for predicting its transport dynamics in groundwater systems. We completed batch experiments to study the interactions of arsenic with a common MnO2(s) mineral, pyrolusite. The reaction kinetics and adsorption isotherm developed from the batch experiments were integrated into a scalable reactive transport m...

The aim of this study was to construct redox- and pH-responsive degradable manganese dioxide (MnO2) nanosheets for cancer theranostic application. The small MnO2 nanosheets were synthesized, and then functionalized by hyaluronic acid (HA), demonstrating excellent stability and tumor-targeting ability. Cisplatin (cis-diamminedichloroplatinum [CDDP]) was absorbed by the nanosheets through a physi...

MnO2 is considered one of the most promising pseudocapactive materials for high-performance supercapacitors given its high theoretical specific capacitance, low-cost, environmental benignity, and natural abundance. However, MnO2 electrodes often suffer from poor electronic and ionic conductivities, resulting in their limited performance in power density and cycling. Here we developed a "conduct...

Nanostructured transition-metal oxides can store high-density energy in fast surface redox reactions, but their poor conductivity causes remarkable reductions in the energy storage of most pseudocapacitors at high power delivery (fast charge/discharge rates). Here it is shown that electron-correlated oxide hybrid electrodes made of nanocrystalline vanadium sesquioxide and manganese dioxide with...

In this study, alkaline solid embeddable MnO2 is used as a reference sensor for concrete environments. The performance characteristics are evaluted in a saturated calcium hydroxide solution, a synthetic concrete pore solution and ordinary Portland cement (OPC) extracts which correspond to he concrete environments. The electrochemical stability of the MnO electrode is studied in the said concret...

Oxidized carbon nanosheets (OCNs), produced from black carbon nanospheres and used as a conductive additive in the supercapacitor electrodes of MnO2 nanorods, can significantly improve the charge-storage performance of the symmetric MnO2-nanorod supercapacitors with a maximum specific energy of 64 W h kg(-1) and power of 3870 W kg(-1). An optimum material composition of the supercapacitor elect...