nano tio2 supported on sio2 (nano tio2@sio2) as a solid lewis acid, was described to be an effective and reusable catalyst for one-pot three-component reaction of benzil, aryl aldehydes and ammonium acetate for the synthesis 2-aryl-4,5-diphenyl-1h-imdazoles synthesis. to explore the high efficacy of the catalytic system the four-component cyclization of benzil, aryl aldehydes, ammonium acetate ...

Development of cheap, abundant and metal-free N-doped carbon materials as high efficiency oxygen reduction electrocatalysts is crucial for their practical applications in future fuel cell devices. Here, three-dimensional (3D) N-doped porous carbon (NPC) materials have been successfully developed by a simple template-assisted (e.g., SiO2 spheres) high temperature pyrolysis approach using shrimp-...

This manuscript describes the preparation and characterization of silica-nickel oxide (SiO2-NiO) xerogel nanocomposite its catalytic application in hydrogenation p-nitrophenol. Hydrochloric acid ammonium hydroxide were used as base catalyst, respectively during synthesis SiO2-NiO. The Fourier Transformation Infra-Red spectroscopic results supported formation silica skeleton structure with corre...

A simple highly versatile and efficient sonochemical synthesis of 1,2,4,5-tetrasubstituted and 2,4,5-trisubstituted imidazoles is achieved by condensation of 1,2-dicarbonyl compound, aldehyde, ammonium acetate and primary amine using antimony trichloride immobilized on silica gel (SiO2-OSbCl2) as a catalyst in ethanol at moderate temperature. Operational simplicity, practicability and applicabi...

The nickel-based catalyst was more active in the reverse water-gas shift reaction, but it is easy to sinter and deactivate high temperature reaction (≥600 °C). A urea-assisted impregnation method utilized create a Ni/SiO2-N increase catalytic stability of Ni-based catalysts. For at least 20 h, process 700 °C remained stable, RWGS conversion rate CO2 close equilibrium rate. catalysts were charac...

Bimetallic Ni-Cu/SiO2 catalysts with different Cu loading (2–5 wt%) were developed for liquid phase selective hydrogenation of furfural to furfuryl alcohol. Among these, bimetallic 2%Ni-X%Cu/SiO2 (X = 2, 5) exhibited better catalytic performances than monometallic 2%Ni/SiO2 and 2%Cu/SiO2. Moreover, the 2%Ni-5%Cu/SiO2 catalyst showed best performance 94% conversion 64% alcohol selectivity. The s...

Nano TiO2 supported on SiO2 (Nano TiO2@SiO2) as a solid Lewis acid, was described to be an effective and reusable catalyst for one-pot three-component reaction of benzil, aryl aldehydes and ammonium acetate for the synthesis 2-aryl-4,5-diphenyl-1H-imdazoles synthesis. To explore the high efficacy of the catalytic system the four-component cyclization of benzil, aryl aldehydes, ammonium acetate ...

In the present study, the core-shell magnetic nanostructure of Fe3O4@SiO2@CeO2 was synthesized to investigate its use as an effective photocatalyst for methylene blue removal. The prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and a vibrating sample magnetometer (VSM). The photocatalytic activity for the Fe3O4@SiO2@CeO2 core-shell magneti...

The performance of the Mn-Na2WO4/SiO2 catalyst for oxidative coupling methane (OCM) has been ascribed to crystalline phases that are not present at reaction temperatures (>700 °C). evolution W and Mn sites structure was monitored via in situ TPO-XRD, -Raman, -XANES spectroscopies. TPO-XRD shows identified on Mn-Na2WO4/SiO2, Na2WO4/SiO2, WO3/SiO2 catalysts room temperature do exist relevant OCM ...