Iodine-doped graphene has been successfully fabricated through a simple, economical, and scalable approach. The new metal-free catalyst can exhibit a high catalytic activity, long-term stability, and an excellent methanol tolerance for the oxygen reduction reaction.

The disposed wastes of zinc industries contain large amounts of heavy metals such as Pb2+ and Cd2+. These elements are considered as hazardous elements to human beings and other organisms. This study aims at introducing the fungal isolates that evolved to be compatible with waste deposits during the time and can absorb Pb2+ and Cd2+ions. During the spring and autumn in 2011, eight samples of se...

We report an operationally simple, metal-free approach for the late-stage introduction of the important lipophilic hydrogen-bond donor motif, SCF2H. This reaction converts diaryl- and dialkyl-disulfides into the corresponding aryl/alkyl-SCF2H through the nucleophilic transfer of a difluoromethyl group with good functional group tolerance. This method is notable for its use of commercially avail...

The first example of metal-free regioselective hydrazination of imidazo[1,2-a]pyridine with diethyl azodicarboxylate is accomplished. This procedure is chemically appealing due to the high degree of functional group tolerance and efficiency in expanding the molecular diversity.

Reactive, thermal degradation of py2Pt[MoCp(CO)3]2, (Me)(cod)PtMoCp(CO)3, orfPt3ðdppmÞ3ðCOÞ1⁄2MoðCpÞ g[BPh4]/Vulcan carbon powder composites affords Pt–Mo/carbon nanocomposites containing metal nanoparticles of approximate compositions, PtMo2, PtMo, or Pt3Mo, widely dispersed on the carbon support. Total metal loadings range from 29–58 wt%. When tested as an anode electrocatalyst in a PEM fuel ...

The direct oxidative coupling reaction has been an attractive tool for environmentally benign chemistry. Reported herein is that the hypervalent iodine catalyzed oxidative metal-free cross-coupling reaction of phenols can be achieved using Oxone as a terminal oxidant in 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP). This method features a high efficiency and regioselectivity, as well as functional-g...

In Direct Metal Laser Sintering objects are created by sequential sintering loose metal powder particles by means of laser technology. When the laser sintering process involves temperature gradients, thermal stresses develop. Corresponding residual stresses induce warping of the densified structure leading to unacceptable tolerance losses. This paper examines the role of laser beam scan pattern...