In this research work, poly (acrylonitrile-butadienestyrene)/polypropylene (ABS/PP) blends were processed by melt compounding in a twin-screw extruder. Upgrading of the thermal characteristics of the obtained materials was attempted by the incorporation of organically modified montmorillonite (OMMT), as well as, by the addition of two types of compatibilizers; polypropylene grafted with maleic ...

Ahstrct-Styrene maleic anhydride copolymers (SMACs) are of particular commercial and academic interest. The bulk copolymer&&ion reaction is characterized by a very fast reaction rate and an important gel effect. The copolymer has a strong tendency to be alternate when maleic anhydride is in excess. In order to obtain a copolymer with less than 50% of incorporated MA, a good quality of mixing mu...

Anhydrous sodium acetate will serve as the catalyst with maleic, chloro-maleic, and methylglutaconic anhydrides, giving yields of 0.54, 0.22, and 1.02 moles CO2 per mole of anhydride. The products of all these reactions are black and brown-black, are soluble in acetone, acetophenone, dioxane, and aqueous alkali and are insoluble in benzene, toluene, ether, chloroform and carbon tetrachloride, a...

Previous studies of the subunit structure of hexosaminidase gave ambiguous results, but suggested that the enzyme was composed of six equally sized subunits. Dissociation of hexosaminidase A with p-chloromercuribenzoate produces an alkylated fragment with mol.wt. approx. 50000, which is converted into hexosaminidase S by treatment with dithiothreitol. Treatment ofnative hexosaminidase A with so...

Based upon the biphenyl 1-(2-naphthyl)-1H-pyrazole-5-carboxylamides reported in our previous communications, we designed and discovered 2-(6-chloro-3-methylsulfonyl)-naphthyl as an optimal factor Xa S1 binding element. Employing a key Diels-Alder reaction of 1,4-dihydro-2,3-benzoxathiin-3-oxide with maleic anhydride and a key Cu(I)-mediated methylsulfonylation, we prepared two biphenyl 1-(2-(6-...

The rate of protein degradation in Zea mays leaves has been estimated by using tritiated water and [(3)H]acetic anhydride as the labeling agents. Both methods circumvent many of the problems usually associated with measuring protein degradation in plants. The half-life of ribulose-1,5-bisphosphate carboxylase protein in second leaves of 13-day-old seedlings under continuous light was found to b...

We investigate the solidiication behavior of a maleic anhydride / polyacrylonitrile mixture in the banded spherulitic regime. In particular , we measure the velocity of the solidiication front and the resulting wavelength of the bands as the undercooling T is varied. The observed dynamics are representative of that seen in a large class of highly viscous uids that have been solidiied well below...

Polietileno de baixa densidade (LLDPE) com comonômeros 1-buteno e 1-octeno foram funcionalizados com anidrido tetrahidroftálico (THA) e anidrido maléico (MA) em solução na presença de peróxido de benzoíla (BPO), de acordo com planejamentos fatoriais. As variáveis testadas foram concentração de anidrido, concentração de peróxido, tempo de reação e tipo de comonômero. As formulações foram analisa...

The title compound, C(31)H(25)NO(6), has a structure related to other 3,4-diaryl-substituted maleic anhydride derivatives which have been shown to be useful as photochromic materials. The dihedral angles between the maleimide ring system and the benzene rings bonded to it are 44.48 (3) and 17.89 (3)°, while the angles between each of the latter rings and the corresponding ether bridging connect...

Renewable aromatics can be conveniently synthesized from furanics by introducing an intermediate hydrogenation step in the Diels-Alder (DA) aromatization route, to effectively block retro-DA activity. Aromatization of the hydrogenated DA adducts requires tandem catalysis, using a metal-based dehydrogenation catalyst and solid acid dehydration catalyst in toluene. Herein it is demonstrated that ...