NO is the primary product of the oxidation of char nitrogen, and in some combustion processes the NO can be reduced on the char surface to give N2O and/or N2. In this study a range of bituminous coals (low, medium and high volatile matter content) were pyrolysed in a fixed bed reactor at various heating rates. Textural characterisation was carried out by measuring true (He) and apparent (Hg) de...

We propose a H2–CO kinetic model which incorporates the recent thermodynamic, kinetic, and species transport updates relevant to high-temperature H2 and CO oxidation. Attention has been placed on obtaining a comprehensive and kinetically accurate model able to predict a wide variety of H2–CO combustion data. The model was subject to systematic optimization and validation tests against reliable ...

The existing methods of synthesis of thermoelectric (TE) materials remain constrained to multi-step processes that are time and energy intensive. Here we demonstrate that essentially all compound thermoelectrics can be synthesized in a single-phase form at a minimal cost and on the timescale of seconds using a combustion process called self-propagating high-temperature synthesis. We illustrate ...

increase of environmental pollution and restricted emission legislations have forced companies to produce automobiles with lower air pollutants. in this respect, discharge of blowby gases into the environment has been prohibited and their recirculation into the combustion chamber is proposed as an alternative solution. in addition, using egr technique to control and reduce nitrogen oxides in in...

Pulse firing offers significant process and productivity benefits, such as improved temperature uniformity and high heat transfer rates to the product load through maximum system turndown and utilizes the system’s burners at their most efficient firing rates. However, overshoot and undershoot is unavoidable. To minimize these effects, the system operates the burner at an enhanced turndown rate....

-The role which low-temperature catalytic combustion should play in the future hydrogen energy system is discussed in comparison with those of conventional flame-type combustion and fuel cells. A hybrid of catalytic and flame combustion is also referred to in the comparison. Screening of catalyst materials proved that several inexpensive oxides of the 3d transition metals were active at interme...

The catalytic properties of Al2O3-supported vanadia with a wide range of VOx surface density (1.4-34.2 V/nm) and structure were examined for the oxidative dehydrogenation of ethane and propane. UV-visible and Raman spectra showed that vanadia is dispersed predominately as isolated monovanadate species below ~2.3 V/nm. As surface densities increase, two-dimensional polyvanadates appear (2.3-7.0 ...

This paper presents a comprehensive optimization approach for enhancing the performance of methanol/diesel Exhaust Gas Recirculation (EGR) engine. Initially, hybrid fuel engine combustion chamber model was developed using AVL-FIRE software, and simulated results were compared with values obtained from bench tests. An orthogonal experimental design employed to optimize five key factors, namely m...

Research has been conducted toward developing technology for co-firing of coal with municipal solid waste (MSW) in order to reduce emissions of chlorinated organic compounds, particularly polychlorinated dibenzo-p-dioxins and furans (PCDDs and PCDFs). Previous benchand pilot-scale research has shown that presence of SO2 can inhibit the PCDD and PCDF formation, and suggested cofiring high-sulfur...