Understanding and manipulating synthesis reactions and crystal growth mechanisms are keys to designing and constructing the morphology and functional properties of advanced materials. Herein, the morphology-controlled synthesis of three-dimensional (3D) ZnO nanoforests is reported via a facile hydrothermal route. Specifically, the respective and synergistic influence of polyethylenimine (PEI) a...

Polycations such as polyethylenimine (PEI) are used in many novel nonviral vector designs and there are continuous efforts to increase our mechanistic understanding of their interactions with cells. Even so, the mechanism of polyplex escape from the endosomal/lysosomal pathway after internalization is still elusive. The "proton sponge " hypothesis remains the most generally accepted mechanism, ...

All-printed organic photodiode arrays on plastic are reported with average specific detectivities of 3.45 × 10(13) cm Hz(0.5) W(-1) at a bias of -5 V. The blade-coated polyethylenimine cathode interlayer and active layer, and screen-printed anode enable precise device performance tunability and excellent homogeneity at centimetric scales. These devices' high operational reverse bias, good linea...

A major challenge in synthetic gene delivery is to quantitatively predict the optimal design of polymer-based gene carriers (polyplexes). Here, we report a consistent, integrated, and fundamentally grounded computational methodology to address this challenge. This is achieved by accurately representing the spatio-temporal dynamics of intracellular structures and by describing the interactions b...

A novel simple and versatile synthetic strategy is developed for the surface modification of boron-doped diamond. In a two-step procedure, polyethyleneimine is adsorbed on the hydrogenated diamond surface and subsequently modified with a model light-harvesting donor-π-bridge-acceptor molecule (coded P1). The sensitized diamond exhibits stable cathodic photocurrents under visible-light illuminat...