The chemically crosslinked metal-complexed chitosans were synthesized by using the ion-imprinting method from a chitosan with four metals (Cu(II), Zn(II), Ni(II) and Pb(II)) as templates and glutaraldehyde as a crosslinker. The influences of adsorption conditions, including molar ratios of crosslinker/chitosan and pH changes, were studied. They were used to investigate for comparative adsorptio...

A semimechanistic multi-reaction kinetic model was developed to describe the enzymatic hydrolysis of a lignocellulosic biomass, creeping wild ryegrass (CWR; Leymus triticoides). This model incorporated one homogeneous reaction of cellobiose-to-glucose and two heterogeneous reactions of cellulose-to-cellobiose and cellulose-to-glucose. Adsorption of cellulase onto pretreated CWR during enzymatic...

Activated carbon prepared from neem oilcake, by pyrolysis accompanied with microwave oven activation is evaluated for the adsorption of Cd(II) and Ni(II) from wastewater. Parameters such as pH, agitation time, metal ion concentration and adsorbent dose are studied. The percent removal increased with pH from 2.0 to 7.0. The adsorption data fit well with Langmuir, Freundlich and Temkin isotherm m...

The use of recoverable sulfur particles will enhance the feasibility and reduce the cost of bioleaching process. Three different forms of sulfur particles, powder, pastilles and pellets were used to study the utilization and recovery of sulfur, used as energy source for thiobacilli in the bioleaching process. The Langmuir isotherm was used to explain the adsorption equilibrium existing between ...

Activated carbon prepared from Ceiba pentandra hulls, an agricultural solid waste by-product, for the removal of copper and cadmium from aqueous solutions has been studied. Parameters such as equilibrium time, effect of pH and adsorbent dose on removal were studied. The adsorbent exhibited good sorption potential for copper and cadmium at pH 6.0. C=O and S=O functional groups present on the car...

Copper is present in different types of industrial effluents, being responsible for environmental pollution. Biosorption of heavy metals can be an effective process for the removal and recovery of heavy metal ions from aqueous solutions. The biomass of marine algae has been reported to have high uptake capacities for a number of heavy metal ions. In this paper, the adsorption properties of a pr...

The presence of toxic heavy metals such as chromium (VI) contaminants in aqueous streams, arising from the discharge of untreated metal containing effluents into water bodies, is one of the most important environmental problems. Adsorption is one of the effective techniques for chromium (VI) removal from wastewater. In the present study, adsorbent is prepared from tamarind seeds and studies are...

A batch sorption process for removal of ammonium ions from aqueous solution using natural zeolite was studied. Tree different particle sizes of zeolite (1-2 mm, 2-4 mm and 4-10 mm) were used in the experiments. Sorption of ammonium ions on natural zeolite were carried out at 298 K with the initial concentrations of ammonium in the range of 1000 – 7000 mg NH4 -N/dm. Equilibrium data were fitted ...

In this study the main physical-chemical characteristics of red ferralitic soil to use as substrate in subsurface wetlands was determined. The P-removal was evaluated in a short-term isotherm batch experiment and in a column percolation experiment. The acid characteristic and high content of iron minerals in the red ferralitic soil facilitated the phosphorus removal. Also the sorption isotherms...

The present work is concerned to remove Cu using the biosorption potential of fungal biomass Aspergillus oryzae. The dry fungal biomass was used to optimize various parameters such as contact time, initial metal ion concentration, pH, biomass loading etc. A maximum of 91% Copper removal was observed in 5 mg/L initial Copper metal ion concentration using dry Aspergillus oryzae biomass. The perce...