a rapid, sensitive and versatile kinetic method is presented for the simultaneous spectrophotometric determination of iodide and iodate by partial least-squares regression (pls) using original and derivate data named as absorbance and rate data. the method is based on the catalytic effect of the cited anions on the reaction rate between ce(iv) and as(iii) in 2 mol l?1 sulfuric acid medium. the ...

the reaction of ch3o2 radicals with acetaldehyde on the solid surface of nh4no3 has been studied in a flow capillary reactor at low pressure and room temperature. the experiments were performed using epr spectrometer combined with the kinetic method of radicals freezing. peroxy radicals revealed an oscillation complex behavior during the process regarding to the phenomenon of radicals multiplic...

In this note we study a minimization problem for a vector of measures subject to a prescribed interaction matrix in the presence of external potentials. The conductors are allowed to have zero distance from each other but the external potentials satisfy a growth condition near the common points. We then specialize the setting to a specific problem on the real line which arises in the study of c...

The exact solution to the hierarchy of nonlinear lattice Boltzmann (LB) kinetic equations in the stationary planar Couette flow is found at nonvanishing Knudsen numbers. A new method of solving LB kinetic equations which combines the method of moments with boundary conditions for populations enables us to derive closed-form solutions for all higher-order moments. A convergence of results sugges...

Ecological, toxicological, and pharmacological research is often concerned with the answer to the question of how a substance is processed within a biological system. The exact knowledge of the corresponding kinetic pattern forms the basis for a useful answer. In order to identify non-linear kinetics, a firstorder approximation method is proposed for complexity-reduction. A simulation study is ...

This paper investigates the asymptotical stabilization of the time-invariant and the time-varying Port-Hamiltonian (PH) systems via a new kinetic energy-shaping (KES) method. Firstly, a desired kinetic energy function is designed for the non-trivial points. Secondly, applying the KES method to the Hamiltonian function with the desired kinetic energy function builds some matching equations. Thir...

A rapid, sensitive and versatile kinetic method is presented for the simultaneous spectrophotometric determination of iodide and iodate by partial least-squares regression (PLS) using original and derivate data named as absorbance and rate data. The method is based on the catalytic effect of the cited anions on the reaction rate between Ce(IV) and As(III) in 2 mol l?1 sulfuric acid medium. The ...

It is well known that for increasingly rarefied flowfields, the predictions from continuum formulation, such as the Navier–Stokes equations lose accuracy. For the high speed diatomic molecular flow in the transitional regime, the inaccuracies are partially attributed to the single temperature approximations in the Navier–Stokes equations. Here, we propose a continuum multiple temperature model ...