The objectives of this study were [1] to conduct some experimental tests of the surface precipitation adsorption model, and [2] to work on the development of a simple yet widely applicable approach to modelling adsorption of inorganic ions on oxide surfaces. The latter represents the first portion of our continuing effort to develop a data base for adsorption of inorganic contaminants in oxide ...

To override the diffusion-limited adsorption step of viral infection, we magnetically synchronized cell attachment. Human immunodeficiency virus type 1-based lentivirus preparations were rendered magnetically reactive by association with magnetite nanoparticles, 50 nm in diameter. Application of a magnetic field resulted in immediate redistribution of the viral inoculum to the cell-associated s...

in this study, aniline-formaldehyde polymer was synthesized and then modified with extra aniline as cross-linker in the presence and absence of ni(ii) as the template to produce ion imprinted poly(aniline-formaldehyde) (iipaf) and non imprinted poly(aniline-formaldehyde)(nipaf) the iipaf was subjected to adsorption, preconcentration and determination of ni(ii) ion in environmental samples. the ...

We have performed a density functional theory investigation on the structural and electronic properties of pristine and Nitrogen-doped TiO2 anatase nanoparticles as the adsorbents for removal and degradation of hydrazine molecules in the environment. We have presented the most stable adsorption configurations and examined the interaction of hydrazine molecule with these doped and undoped nanopa...

We have performed density functional theory (DFT) quantum periodic calculations to investigate the interaction between atomic Pd and oxide surfaces of ZrO2(110), MgO(100), and CeO2(110). In this calculation, Pd adsorption energy on the surface oxygen atom sites of those oxide surfaces correlated with the position of the d electron density center of Pd atom except for on the surface metal atom s...

Many bacteriophage populations display heterogeneity in their adsorption characteristics; a portion of the phage population remains free in solution throughout adsorption experiments (residual fraction). This residual fraction generally constitutes a minority of phages that exhibit significantly slower adsorption kinetics than the main phage stock (main fraction). While this phenomenon is likel...

Adsorption of different oxidation species of selenium (Se), selenate (SeO4) and selenite (SeO3), with varying pHs (2-10) and ionic strengths (I=0.01 M, 0.1 M and 1.0 M NaNO3) was measured on quartz, aluminum oxide, and synthetic iron oxide (ferrihydrite) using batch reactors to obtain a more detailed understanding of the adsorption mechanisms (e.g., innerand outer-sphere complex). In addition t...

We have studied dissociative H2 adsorption on the H/Si~100! surface by means of pseudopotential density functional theory calculations. This work is directly motivated by the observations of Biederman et al. @Phys. Rev. Lett., 83, 1810 ~1999!#: ‘‘H2 adsorption is significantly promoted in an interdimer configuration of two adjacent singly occupied dimers.’’ We find that there is no adsorption b...

In this study, the adsorption of certain water-soluble cationic dyes, (basic blue 9, basic blue 12, basic blue 17, brilliant cresyl blue, janus green B, basic green 4, basic violet 1, basic violet 3, and thionin) onto TriSyl silicas by batch adsorption at 25◦C was investigated. In the adsorption experiments, Langmuir type adsorption in the Giles classification system was found. Binding paramete...

bioremediation of heavy metals remains a major challenge in environmental biotechnology. biosorption is a novel technique for decreasing metal ion content in the waste water. biosorption experiments for cu (ii) were investigated in this study using bacteria isolated from the industrial effluent. the results showed that the dead cells of pseudomonas sp. were an efficient adsorbent of cu (ii). fo...