The electrochemical reduction of oxygen generated superoxide ion and the electrochemical oxidation of ferrocene yielded the ferricenium ion. Both of these ion radicals were produced alternately in the same solution by pulsing the electrode potential between the reduction potential of oxygen and the oxidation potential of ferrocene. The homogeneous electron transfer reaction between superoxide i...

The electtical conductivity existing in electrified clouds is computed under the assumption that a primary positive dipole charge distribution exists within the cloud and that the small ion concentrations are controlled by the rate of ion production from cosmic ray ionization, and by the rates of ion loss from the separate processes of ion recombination, diffusion, and conduction. The results s...

Superoxide ion (O2˙-) forms a stable 1 : 1 complex with scandium hexamethylphosphoric triamide complex [Sc(HMPA)(3)(3+)], which can be detected in solution by ESR spectroscopy. Electron transfer from O2˙- -Sc(HMPA)(3)(3+) complex to a series of p-benzoquinone derivatives occurs, accompanied by binding of Sc(HMPA)(3)(3+) to the corresponding semiquinone radical anion complex to produce the semiq...

When laser light impinges upon a liquid-liquid interface between an optically transparent aqueous and opaque organic phase from the aqueous to organic phase, the temperature at the interface and the interfacial region rises. Using this rise in temperature, we have proposed and developed thermal modulation voltammetry at an interface between two immiscible electrolyte solutions (TMV-ITIES) and h...

Holliday Junctions are critical DNA intermediates central to double strand break repair and homologous recombination. The junctions can adopt two general forms: open and stacked-X, which are induced by protein or ion binding. In this work, fluorescence spectroscopy, metal ion luminescence and thermodynamic measurements are used to elucidate the ion binding site and the mechanism of junction con...

Electron transfer in collisions between Rydberg atoms and targets that attach free low-energy electrons can lead to the formation of heavy-Rydberg ion-pair states comprising a positive-negative ion pair that orbit each other at large separations weakly bound by their mutual electrostatic attraction. It is shown that measurements of the velocity distribution of the ion-pair states produced in su...