The selective oxidation of lactose by molecular oxygen has been studied in a batch reactor containing an aqueous slurry of 0.5 kmol m-1 reactant and 1.0 kg m-3 catalyst. The in situ Bi promotion of a commercial Pd-C catalyst resulted in 100% selectivity to sodium lactobionate up to conversions of 95% in the pH range 7-10 and at temperatures up to 333 K. Performing the reaction under such condit...

A water-soluble and air-stable Pd(NH3)2Cl2/cationic 2,2'-bipyridyl system was found to be a highly-efficient and reusable catalyst for the coupling of aryl iodides and alkenes in neat water using Bu(3)N as a base. The reaction was conducted at 140 degrees C in a sealed tube in air with a catalyst loading as low as 0.0001 mol % for the coupling of activated aryl iodides with butyl and ethyl acry...

Sustainable solvent-free continuous flow epoxidation of biorenewable terpenes using a recyclable tungsten-based polyoxometalate phase transfer catalyst and benign H2O2 oxidant.

Inverse filtering of room transfer functions (RTFs) is considered an attractive approach for speech dereverberation given that the time invariance assumption of the used RTFs holds. However, in a realistic environment, this assumption is not necessarily guaranteed, and the performance is degraded because the RTFs fluctuate over time and the inverse filter fails to remove the effect of the RTFs....

one distinct concentration of copper ions was embedded into the silica matrix to xerogel form using copper source cu(no3)2∙3h2o. the xerogel samples were prepared with using hydrolysis and condensation reactions of tetraethyl ortho-silicate (teos) by the sol-gel method. in this investigation, new molar ratio of h2o/teos was determined to be 11.7. also, the necessary amount of tri-hydrated coppe...

The coordination polymerization of ethylene in water as a reaction medium was studied. Rubbery amorphous branched polyethylene was obtained when a known cationic diimine-substituted methyl complex was employed as a catalyst precursor. High rates of up to 900 TOh(-1) (turnover frequency) were observed. In contrast to solution polymerization in an organic solvent, the rate of suspension polymeriz...

Hydrogenation of various types of oleochemicals is a major unit operation in industry. Natural fatty alcohols are important raw materials for surfactants and lubricants and can be produced by catalytic hydrogenation of fatty acid methyl esters (FAME). Commercial multiphase processes are necessarily operated at high pressures and high hydrogen-to-ester mole ration owing to low solubility of hydr...

A method is presented for predicting the total response, in both frequency and time, of an unknown linear system when only the measured continuous wave (cw) magnitude is available. The approach is based on approximating the square of the measured magnitude by a rational function, from which various system transfer functions in terms of complex frequency are deduced. These transfer functions may...

A plant can track an input command signal if it is driven by a controller whose transfer function approximates the inverse of its transfer function. A stable inverse can be obtained even if the plant is nonminimum-phase. No direct feedback is used, except that the plant output is monitored and utilized to adapt the parameters of the controller. A model-reference inverse control system can learn...