The thermodynamic properties of gases have been understood primarily through phase diagrams of bulk gases. However, observations of gases confined in a nanometer space have posed a challenge to the principles of classical thermodynamics. Here, we investigated interfacial structures comprising either O2 or N2 between water and a hydrophobic solid surface by using advanced atomic force microscopy...

The work investigates the role of interfacial potential in defining antimicrobial propensity of ZnO nanoparticle (ZnONP) against different Gram positive and Gram negative bacteria. ZnONPs with positive and negative surface potential are tested against different bacteria with varying surface potentials, ranging -14.7 to -23.6 mV. Chemically synthesized ZnONPs with positive surface potential show...

The purpose of the present paper is to develop light beam method to measurement of interfacial area in a rectangular gas-liquid bubble column. Total interfacial area can be determined in bubble column filled by transparent liquid by light transmission method. According to pervious researches, the fraction of parallel light is function of interfacial area and optical path l...

Low-energy forward-recoil spectrometry studies show that the interface between polystyrene sAd and a miscible blend of two poly(styrene-co-4-bromostyrene)s sB:Cd has an interfacial excess of B, z B, where B is the component with the lower bromostyrene level. At 170 ±C, z B increases with the bulk volume fraction of B, fB`, has a maximum near 0.25, and then decreases. These results are in qualit...

Strength and toughness are two mechanical properties that are generally mutually exclusive but highly sought-after in the design of advanced composite materials. There has only been limited progress in achieving both high strength and toughness in composite materials. However, the fundamental underlying mechanics remain largely unexplored, especially at the nanoscale. Inspired by the lamellar s...

Alkaline/surfactant/polymer (ASP) flooding has been extensively applied to enhancing oil recovery. As an oil displacement agent, pe1troleum sulfonate (PS) is widely used in ASP pilot experiments. It is very important to find a petroleum sulfonate with a high interfacial activity and low adsorption loss. Anionic surfactant petroleum sulfonate is synthesized in a single-tube film sulfonation reac...

For further analysis of the effect of nano-doping on the properties of high polymers and research into the mechanism behind modified interfacial hydrogen bonds, a study on the formation probability of nano-SiO2/meta-aramid fibre interfacial hydrogen bonds and the strengthening mechanism behind interfacial hydrogen bonds on the thermal stability of meta-aramid fibres using molecular dynamics is ...

this paper reports on preparation of polyamide membrane with addition of silver nanoparticles (agnps). agnps act as antibacterial agents that are less susceptible to membrane’s biofouling by interfacial polymerization (ip) method. agnps was synthesized via green route which has been reported previously. attenuated total reflectance-fourier transform infrared spectroscopy (atr-ftir), field emiss...

We present a theory that is able to account quantitatively for the surface and interfacial tensions of different electrolyte solutions. It is found that near the interface, ions can be separated into two classes: the kosmotropes and the chaotropes. While the kosmotropes remain hydrated near the interface and are repelled from it, the chaotropes loose their hydration sheath and become adsorbed t...