نتایج جستجو برای: interfacial area

تعداد نتایج: 604570  

Journal: :Fire 2023

The aim of the present work is to account for polydisperse effects in a two-phase flow with simple and fast method. Polydisperse flows arise numerous applications. Fire sprinkler systems are relevant examples as they release clouds droplets. Another example created by detonation an explosive charge surrounded liquid layer. In such situation, material interfaces initially consists carrier gas ph...

Journal: :Faraday discussions 2013
Santos Alexandre P dos Yan Levin

We present a theory that is able to account quantitatively for the surface and interfacial tensions of different electrolyte solutions. It is found that near the interface, ions can be separated into two classes: the kosmotropes and the chaotropes. While the kosmotropes remain hydrated near the interface and are repelled from it, the chaotropes loose their hydration sheath and become adsorbed t...

Journal: :Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 2004
Toshinori Morisaku Hiroharu Yui Tsuguo Sawada

We present a new experimental system to observe reactions in biomembranes by combining laser spectroscopic techniques with phospholipid monolayers formed at oil/water interfaces. The system can monitor reactions through changes in interfacial tension at oil/water interfaces induced by the reactions under non-destructive and non-contact conditions. In addition, oil/water interfaces with defined ...

Journal: :Physical review. E, Statistical, nonlinear, and soft matter physics 2002
R Tuinier H N W Lekkerkerker D G A L Aarts

The interaction between two spheres in a solution of nonadsorbing polymers, with excluded volume interaction, is calculated from the depletion layers around the spheres using the generalized Gibbs adsorption equation. By combining the bulk correlation length with the curvature-dependent interfacial tension between a sphere and the surrounding polymer solution [Hanke, Eisenriegler, and Dietrich,...

Journal: :Scientific reports 2016
Meyer B Jackson

Studies of the partitioning of hydrophobic solutes between water and nonpolar solvents provide estimates for the energy cost of creating hydrophobic-water contacts. This energy is a factor of three lower than the work of adhesion derived from interfacial tension measurements. This discrepancy noted by Tanford in 1979 is widely viewed as a serious challenge to our understanding of hydrophobic in...

2000
Rudolf J. Held Michael A. Celia

Computational pore-scale network models describe two-phase porous media ̄ow systems by resolving individual interfaces at the pore scale, and tracking these interfaces through the pore network. Coupled with volume averaging techniques, these models can reproduce relationships between measured variables like capillary pressure, saturation, and relative permeability. In addition, these models all...

2006
E. Alvarez M. A. Cancela R. Maceiras J. M. Navaza Lope Gómez

INTRODUCTION Bubble columns are widely used in industrial gas-liquid operations (e.g. gas-liquid reactions, fermentations) in chemical and biochemical processes industries, due to their simple construction, low operating cost and high-energy efficiency. In all these processes, gas hold-up and bubble size are important design parameters since they define the gasliquid interfacial area available ...

Journal: :Physical chemistry chemical physics : PCCP 2015
Tony Jaumann Juan Balach Markus Klose Steffen Oswald Ulrike Langklotz Alexander Michaelis Jürgen Eckert Lars Giebeler

Silicon is a promising negative electrode for secondary lithium-based batteries, but the electrochemical reversibility of particularly nanostructured silicon electrodes drastically depends on their interfacial characteristics, commonly known as the solid electrolyte interface (SEI). The beneficial origin of certain electrolyte additives or different binders is still discussed controversially ow...

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