Carboxymethyl cellulose is widely used in many industrial aspects and also in laboratory due to its good biocompatibility. However, special researches on infrared especially aiming at the hydrogen bonds structure of carboxymethyl cellulose were relatively poor. We demonstrate here a full view of infrared spectroscopy in the temperature range of 40–220 C, mainly aiming at the hydrogen bonds in t...

We demonstrate long-term size stabilization of surface-supported liquid aerosols of salt-water. Single tapered optical fibers were used to couple the light from independent heating and probe lasers into individual microdroplets that were kept on a superhydrophobic surface in a high-humidity chamber. Size stabilization of microdroplets resulted from competition between resonant absorption of the...

We study the ionization dynamics of Ar clusters exposed to ultrashort near-infrared (NIR) laser pulses for intensities well below the threshold at which tunnel ionization ignites nanoplasma formation. We find that the emission of highly charged ions up to Ar^{8+} can be switched on with unit contrast by generating only a few seed electrons with an ultrashort extreme-ultraviolet (XUV) pulse prio...

Experimental A stainless steel ultra high vacuum (UHV) chamber, pumped by a turbo molecular pump backed by a mechanical pump, providing a base pressure of 5X10 torr after bake out, was used for temperature programmed desorption (TPD) experiments with a typical heating rate of 2.5 K/s. Samples could be cooled below 100 K via a liquid nitrogen dewar and heated up to 1300 K via resistive heating. ...

Hydrogen storage properties of two ball-milled composites of Ca(NH2)2+2LiH and CaH2+2LiNH2 were investigated as a series of searching studies of high performance hydrogen storage materials. About 4.5 mass% hydrogen is desorbed from about 100 °C and the thermal desorption profiles show a peak around 200 and 220 °C for the composites of CaH2+2LiNH2 and Ca(NH2)2+2LiH, respectively, under a helium ...

A technique for measuring interdiffusion in multilayer materials during rapid heating using X-ray reflectivity is described. In this technique the sample is bent to achieve a range of incident angles simultaneously, and the scattered intensity is recorded on a fast high-dynamic-range mixed-mode pixel array detector. Heating of the multilayer is achieved by electrical resistive heating of the si...

[1] Aerosols absorb solar radiation thus changing the atmospheric temperature profile but the overall magnitude of this effect is not known. To that end, Saharan dust emissions over the Atlantic Ocean provide an opportunity to examine aerosol-related heating via satellite imaging. A major difficulty, however, is disentangling a straightforward heating signal caused by the absorbing dust from a ...

We describe an original apparatus comprising of an acoustic levitator enclosed within a pressure-compatible process chamber. To characterize any chemical and physical modifications of the levitated particle, the chamber is interfaced to complimentary, high-sensitivity Raman (4390-170 cm(-1)), and Fourier transform infrared (FTIR) (10,000-500 cm(-1)) spectroscopic probes. The temperature of the ...

We present a method for calculating the infrared emission from a population of dust grains heated by starlight, including very small grains for which stochastic heating by starlight photons results in hightemperature transients. Because state-to-state transition rates are generally unavailable for complex molecules, we consider model polycyclic aromatic hydrocarbon (PAH), graphitic, and silicat...

Responsive systems sensitive to near-infrared (NIR) light are promising for triggered release due to efficient deep tissue penetration of NIR irradiation relative to higher energy sources (e.g., UV), allowing for spatiotemporal control over triggering events with minimal potential for tissue damage. Herein, we report star polymers containing thermally-labile azo linkages that dissociate during ...