trifluoromethylated organic compounds, especially chiral quaternary alcohols bearing trifluoromethyl group are of important intermediates in drugs, agrochemicals and etc.an efficient epoxidation of β-cf3-β,β-disubstituted unsaturated ketones (6) has been developed with environmental benign hydrogen peroxide as the oxidant and f5-substituted chiral quaternary ammonium salt (1g or 5) derived from...

gem-dihydroperoxides as nearly stable peroxidic derivatives of aldehydes and ketones are known important intermediates in synthesis of anti-malaria drugs. also, because containing high concentration of peroxidic oxygen, recently, some of these compounds have been used as solid, efficient and powerful oxidants in many oxidation organic reactions. generally, these compounds are synthesized via pe...

In the presence of hydrogen peroxide and either potassium iodide, sodium chloride, or potassium bromide, purified human myeloperoxidase was rapidly lethal to several species of Candida. Its candidacidal activity was inhibited by cyanide, fluoride, and azide, and by heat inactivation of the enzyme. A hydrogen peroxidegenerating system consisting of d-amino acid oxidase, flavine-adenine dinucleot...

When hydrogen peroxide is mixed with caustic soda, an auto-accelerating reaction can lead to gen­ eration of significant amounts of heat and oxygen. On the basis of experiments using typical pulp mill process con­ centration and temperatures, a relatively simple kinetic model has been developed. Evaluation of these model results reveals that hydrogen peroxide-caustic soda systems are extremely ...

In this and following papers, the properties of two new catalytically active enzyme-substrate compounds of catalase are given. Paper I gives spectroscopic data, Paper II and III, data on kinetics and activity, and, in Paper IV, the reactions of these enzyme-substrate compounds with hydrogen peroxide are discussed. The red catalase ethyl hydrogen peroxide compound studied by Stern (1) is charact...

The purpose of this investigation was to provide quantitative data showing the effect of oxidizing agents on wool as a basis for studying all processes in which wool is exposed to oxidation reactions. The work reported in this paper deals only with the effect of hydrogen peroxide. Data are presented showing the effects on wool of varying the concentration, temperature, and pH of the hydrogen pe...

In this work we tested viability, proliferation, and vulnerability of neural cells, after continuous radiofrequency (RF) electromagnetic fields exposure (global system for mobile telecommunications (GSM) modulated 900 MHz signal at a specific absorption rate (SAR) of 1 W/kg and maximum duration 144 h) generated by transverse electromagnetic cells. We used two cellular systems, SN56 cholinergic ...

There has been recent concern about the inadvertent exposure of dentin with patent tubules as well as gingiva to bleaching systems containing 10-15% carbamide peroxide or 2-10% hydrogen peroxide for more than a few minutes. The aims of the present study were: (1) to determine the cytotoxicity of dilutions of hydrogen peroxide in cell culture; (2) to measure hydrogen peroxide diffusion from blea...

Rapid detection of the hydrogen peroxide precursor of peroxide explosives is required in numerous security screening applications. We describe a highly sensitive and selective amperometric detection of hydrogen peroxide vapor at an agarose-coated Prussian-blue (PB) modified thick-film carbon transducer. The sensor responds rapidly and reversibly to dynamic changes in the level of the peroxide v...