eethylene polymerization catalysts became available in an enormous variety. the challenge in this research is to find catalysts that are able to connect ethylene molecules in such a way that not only linear chains are produced but variations like branched materials that possess very interesting mechanical properties like linear low density polyethylene (lldpe). in this contribution, three diffe...

A bimetallic heme-DNA cofactor, containing an iron and a copper center, was synthesized for the design of novel hybrid catalysts for stereoselective synthesis. The cofactor was used for the reconstitution of apo-myoglobin. Both the cofactor alone and its myoglobin adduct were used to catalyze a model Diels Alder reaction. Stereoselectivity of this conversion was analyzed by chiral HPLC. Reactio...

In this work, we report a new photocatalytic system that links multifunctional semiconductor nanocrystals with emerging water-soluble molecular catalysts made of earth-abundant elements for H2 generation [Ni(P2RN2R')2(BF4)2]4-, R = Ph, R' = [PhSO3]- (NiS). This noble metal free hybrid exhibits remarkable catalytic activity with a turnover number of 511 for H2 production and a photon-to-H2 conve...

Inclusion complexes of cyclodextrins with organometallic coordination compounds of Pd, Pt, Rh, Fe, Ni, and Ru have been used to produce porous metal-silica hybrid materials. The cyclodextrins are templates for the structure of the silica and lead to a uniform “wormtype” pore system. After the templating step the organometallic compounds can be employed as in situ precursors for the preparation ...

Cyclopentadienyl (Cp) Ni(ii) complexes [CpNiL][PF6] containing hybrid N,C chelating benzothiazolyl NHC ligands (L1 = 1-(2-benzothiazolyl)-3-methylimidazol-2-ylidene, ; L2 = 1-(2-benzothiazolyl)-3-allylimidazol-2-ylidene, ; L3 = 1-(2-benzothiazolyl)-3-benzylimidazol-2-ylidene, ) have been synthesized and fully characterized. The catalytic activity of in some C-C bond formation reactions has been...

Bifunctional chiral urea-containing quaternary ammonium salts can be straightforwardly synthesised in good yield and with high structural diversity via a scalable and operationally simple highly telescoped sequence starting from trans-1,2-cyclohexanediamine. These novel hybrid catalysts were systematically investigated for their potential to control glycine Schiff bases in asymmetric addition r...

Combining enzymatic and single-metal-atom catalysis is a promising approach for green chemical synthesis. We herein report one-pot chemoenzymatic cascade reaction to asymmetric synthesize (R)-1-(4-biphenyl) ethanol by using the highly active selective enzyme-metal-single-atom hybrid as catalyst. demonstrate that Pd single atoms anchored lipase (Pd1/CALB-P) can efficiently drive reactions in aqu...