The introduction of photoactive guest molecules into a spin crossover 3D metal organic framework alters the switchable properties both host and guest.

Viologens are among the most studied guests for cucurbit[8]uril (CB[8]) and their complexation is usually driven by bipyridyl core inclusion inside cavity to maximize both hydrophobic cation-dipole interactions. The presence of alkyl substituents on guest alters this mode, switching aliphatic chain in U-folded conformation. Herein, we report a thorough study influence length binding mode methyl...

Modeling the structure of natively disordered peptides has proved difficult due to the lack of structural information on these peptides. In this work, we use a novel application of the host-guest method, combining folding theory with experiments, to model the structure of natively disordered polyglutamine peptides. Initially, a minimalist molecular model (C(alpha)C(beta)) of CI2 is developed wi...

This paper proposes a technique to achieve asymmetric multiple OSes environment for symmetric multiprocessors. The system has a host OS and guest OSes: L4 microkernel and their servers run as the host OS, and modified Linux runs as the guest OS. OS manager which is one of the servers on the host OS manages the guest OSes. Our approach avoids a lot of execution overheads and modification costs o...

A series of resorcinarene host-amphiphilic guest complexes have been developed where guest orientation in the host is drastically influenced by pH. Guests appended with a trimethylammonium and a tert-butyl group switch orientation by 180° in response to a buildup of negative charge in the cavitand host.

BACKGROUND Curcumin analogs, including the novel compound NC 2067, are potent cytotoxic agents that suffer from poor solubility, and hence, low bioavailability. Cyclodextrin-based carriers can be used to encapsulate such agents. In order to understand the interaction between the two molecules, the physicochemical properties of the host-guest complexes of NC 2067 with β-cyclodextrin (CD) or β-cy...

We report the synthesis of MOF-on-MOF hybrids with core–shell and core–satellite structures in one selected MOF host–guest couple by controlling heterogeneous nucleation homogeneous growth guest MOFs.

Carbon dots, generally small carbon nanoparticles with various forms of surface passivation, have achieved the performance level of semiconductor quantum dots in the green spectral region, but their absorption and fluorescence in red/near-IR are relatively weaker. Conceptually similar to endofullerenes, host-guest carbon dots were designed and prepared with red/near-IR dyes encapsulated as gues...

This study offers a detailed mechanistic investigation of host-guest encapsulation behavior in a new enzyme-mimetic metal-ligand host and provides the first observation of a conformational selection mechanism (as opposed to induced fit) in a supramolecular system. The Ga4L4 host described features a C3-symmetric ligand motif with meta-substituted phenyl spacers, which enables the host to initia...

Code sandboxing is useful for many purposes, but most sandboxing techniques require kernel modifications, do not completely isolate guest code, or incur substantial performance costs. Vx32 is a multipurpose user-level sandbox that enables any application to load and safely execute one or more guest plug-ins, confining each guest to a system call API controlled by the host application and to a r...